Self-assembly of a pseudo-tetrahedral Zn(II) complex with a chiral reduced Schiff base into a helical superstructure

被引：18

作者：

Muppidi, VK ^{[1
]}

Zacharias, PS ^{[1
]}

Pal, S ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 06期

关键词：

zinc(II) complex; tetrahedral; chiral; crystal structure; helical;

D O I：

10.1016/j.inoche.2005.03.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A pseudo-tetrahedral Zn(II) complex with an N,O-donor chiral reduced Schiff base N-(2-hydroxy-5-nitrobenzyl)-(R)-alpha-methylbenzylamine (HL) crystallize in the non-centrosymmetric space group P3(1). The [ZnL2] molecules having the Delta configuration assemble via intermolecular N-H center dot center dot center dot O and C-H center dot center dot center dot O interactions into a right-handed 3(1) helix. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：543 / 547

页数：5

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