Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations

被引：12
作者：
Chen, Xiaoyu [1 ,2 ]
Gao, Feng [3 ]
Yang, Wuqin [1 ]
机构：
[1] China Univ Min & Technol, Sch Safety, Xuzhou 221008, Peoples R China
[2] Nanjing Univ, Nanjing Natl Lab Microstruct, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[3] Jiangsu Normal Univ, Jiangsu Key Lab Green Synthet Chem Funct Mat, Sch Chem & Chem Engn, Xuzhou 221116, Peoples R China
来源：
SCIENTIFIC REPORTS | 2016年 / 6卷
基金：
中国国家自然科学基金;
关键词：
THIANTHRENE; MONOMERS; TRIMER;
D O I：
10.1038/srep29314
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Salts containing radical cations of 1,2,4,5-tetrakis(isopropylthio) benzene (TPB) and 1,2,4,5-tetrakis( ethylthio) benzene (TEB) have been successfully synthesized with SbF6-. These newly synthesized salts have been characterized by UV-Vis absorption, EPR spectroscopy, conductivity measurement, single crystal X-ray diffraction analysis as well as DFT calculation. This study raises the first crystal structure of conductive pi-stacking radical cation with single phenyl ring and reveals their conductivity has relationship with the stack structure which affected by the substituent.
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页数：9
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