Group 3-centred dehydrocoupling of Me2NH•BH3

被引：61

作者：

Hill, Michael S. ^{[1
]}

Kociok-Koehn, Gabriele ^{[1
]}

Robinson, Thomas P. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 40期

基金：

英国工程与自然科学研究理事会;

关键词：

CHEMICAL HYDROGEN STORAGE; AMMONIA-BORANE; CATALYZED DEHYDROGENATION; AMIDOBORANE COMPLEXES; AMINE-BORANES; CALCIUM; DECOMPOSITION; ROUTE; BONDS;

D O I：

10.1039/c0cc02810j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stoichiometric and catalytic reactions of group 3 (Sc, Y) amides with Me2NH center dot BH3 result in formation of the corresponding amidoborane derivatives and dehydrogenative coupling of two amine borane fragments under mild conditions.

引用

页码：7587 / 7589

页数：3

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