Vibrational anharmonicities revealed by coherent two-dimensional infrared spectroscopy

被引：256

作者：

Golonzka, O ^{[1
]}

Khalil, M ^{[1
]}

Demirdöven, N ^{[1
]}

Tokmakoff, A ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

PHYSICAL REVIEW LETTERS | 2001年 / 86卷 / 10期

关键词：

D O I：

10.1103/PhysRevLett.86.2154

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Two-dimensional infrared photon echo spectroscopy has been used to describe the anharmonic nuclear potential of two coupled molecular vibrations. The two-dimensional spectrum shows diagonal and of diagonal features, each composed of two peaks. The splitting between these peaks is directly related to the anharmonicity, while the relative amplitude of the diagonal and off-diagonal features describes the projection angle between interacting dipoles.

引用

页码：2154 / 2157

页数：4

共 15 条

[1] Two-dimensional infrared spectroscopy of peptides by phase-controlled femtosecond vibrational photon echoes
Asplund, MC
Zanni, MT
Hochstrasser, RM
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2000, 97 (15) : 8219 - 8224
[2] SUBPICOSECOND TIME-RESOLVED IR SPECTROSCOPY OF THE VIBRATIONAL DYNAMICS OF RH(CO)2(ACAC)
BECKERLE, JD
CASASSA, MP
CAVANAGH, RR
HEILWEIL, EJ
STEPHENSON, JC
[J]. CHEMICAL PHYSICS, 1992, 160 (03) : 487 - 497
[3] Structure of the amide I band of peptides measured by femtosecond nonlinear-infrared spectroscopy
Hamm, P
Lim, MH
Hochstrasser, RM
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (31): : 6123 - 6138
[4] The two-dimensional IR nonlinear spectroscopy of a cyclic penta-peptide in relation to its three-dimensional structure
Hamm, P
Lim, M
DeGrado, WF
Hochstrasser, RM
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1999, 96 (05) : 2036 - 2041
[5] Two-dimensional electronic spectroscopy
Hybl, JD
Albrecht, AW
Faeder, SMG
Jonas, DM
[J]. CHEMICAL PHYSICS LETTERS, 1998, 297 (3-4) : 307 - 313
[6] KHALIL M, IN PRESS CHEM PHYS
[7] Multidimensional femtosecond correlation spectroscopies of electronic and vibrational excitations
Mukamel, S
[J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2000, 51 : 691 - 729
[8] Femtosecond two-dimensional spectroscopy from anharmonic vibrational modes of molecules in the condensed phase
Okumura, K
Tanimura, Y
[J]. JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (07) : 2267 - 2283
[9] Vibrational echoes: a new approach to condensed-matter vibrational spectroscopy
Rector, KD
Fayer, MD
[J]. INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 1998, 17 (03) : 261 - 306
[10] Vibrational anharmonicity and multilevel vibrational dephasing from vibrational echo beats
Rector, KD
Kwok, AS
Ferrante, C
Tokmakoff, A
Rella, CW
Fayer, MD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (24) : 10027 - 10036

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