Utilization of renewable sources of biogas for small-scale production of liquid fuels

被引:16
作者
Arutyunov, Vladimir [1 ]
Nikitin, Alexey [1 ]
Strekova, Ludmila [1 ]
Savchenko, Valery [2 ]
Sedov, Igor [2 ]
机构
[1] Russian Acad Sci, NN Semenov Fed Res Ctr Chem Phys, Kosygina 4, Moscow 119991, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Av Ac Semenova 1, Chernogolovka 142432, Moscow Oblast, Russia
关键词
Biofuels; Biogas; Matrix conversion; Syngas; Fischer-Tropsch synthesis; FISCHER-TROPSCH-SYNTHESIS; COBALT CATALYSTS; NATURAL-GAS; SYNGAS;
D O I
10.1016/j.cattod.2020.06.057
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Low energy density in agricultural or biotechnological raw materials dictates the need for their local processing. Small-scale agricultural products or waste processing plants can`t profitably use technologies common in largescale petrochemistry, including the complex and expensive process of steam reforming of biogas into syngas for its subsequent conversion to liquid fuel. The work suggests using small-scale sources of inexpensive and easily obtained biogas and other renewable hydrocarbon gases for the production of liquid biofuel by their air conversion in recently developed matrix reformers into low-cost nitrogen-rich syngas, followed by Fischer-Tropsch synthesis in a cascade of sequential reactors. Autothermal matrix reformers are very compact, simple in design, have several times more specific volume capacity than traditional technologies, and allow processing biogas with a high concentration of CO2. The advantages of low-cost conversion of biogas to liquid fuel based on nitrogenenriched syngas with subsequent Fischer-Tropsch synthesis are discussed.
引用
收藏
页码:23 / 27
页数:5
相关论文
共 22 条
[1]   Technologies for large-scale gas conversion [J].
Aasberg-Petersen, K ;
Hansen, JHB ;
Christensen, TS ;
Dybkjaer, I ;
Christensen, PS ;
Nielsen, CS ;
Madsen, SELW ;
Rostrup-Nielsen, JR .
APPLIED CATALYSIS A-GENERAL, 2001, 221 (1-2) :379-387
[2]   Prospects of Conversion of Hydrocarbon Gases to Liquid Products Based on Nitrogen-Rich Synthesis Gas [J].
Arutyunov, V. S. ;
Strekova, L. N. ;
Savchenko, V. I. ;
Sedov, I. V. ;
Nikitin, A. V. ;
Eliseev, O. L. ;
Kryuchkov, M. V. ;
Lapidus, A. L. .
PETROLEUM CHEMISTRY, 2019, 59 (04) :370-379
[3]   Experimental studies of natural gas to synthesis gas converters based on permeable cavity matrices [J].
Arutyunov, V. S. ;
Savchenko, V. I. ;
Sedov, I. V. ;
Shmelev, V. M. ;
Nikitin, A. V. ;
Fokin, I. G. ;
Eksanov, S. A. ;
Shapovalova, O. V. ;
Timofeev, K. A. .
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2016, 89 (11) :1816-1824
[4]   Syngas and hydrogen production in a volumetric radiant burner [J].
Arutyunov, V. S. ;
Shmelev, V. M. ;
Sinev, M. Yu ;
Shapovalova, O. V. .
CHEMICAL ENGINEERING JOURNAL, 2011, 176 :291-294
[5]   3D Matrix Burners: A Method for Small-Scale Syngas Production [J].
Arutyunov, Vladimir S. ;
Shmelev, Vladimir M. ;
Rakhmetov, Ayan N. ;
Shapovalova, Oksana V. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (05) :1754-1759
[6]   Fischer-Tropsch synthesis over γ-calumina-supported cobalt catalysts:: Effect of support variables [J].
Borg, Oyvind ;
Erib, Sigrid ;
Blekkan, Edd A. ;
Storsaeter, Solvi ;
Wigum, Hanne ;
Rytter, Erling ;
Holmen, Anders .
JOURNAL OF CATALYSIS, 2007, 248 (01) :89-100
[7]   Fischer-Tropsch refining: technology selection to match molecules [J].
de Klerk, Arno .
GREEN CHEMISTRY, 2008, 10 (12) :1249-1279
[8]   FISCHER-TROPSCH SYNTHESIS OVER IRON CATALYSTS [J].
DRY, ME .
CATALYSIS LETTERS, 1991, 7 (1-4) :241-251
[9]   Synthesis gas technology large-scale applications [J].
Dybkjaer, Ib ;
Aasberg-Petersen, Kim .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 94 (04) :607-612
[10]  
Jess A, 2001, CHEM ENG TECHNOL, V24, P27, DOI 10.1002/1521-4125(200101)24:1<27::AID-CEAT27>3.0.CO