cis-vinylphosphonates and 1,3-butadienylphosphonates by zirconation of 1-alkynylphosphonates

被引：47
作者：
Quntar, AA [1 ]
Srebnik, M [1 ]
机构：
[1] Hebrew Univ Jerusalem, Sch Pharm, Dept Med Chem & Nat Prod, IL-91120 Jerusalem, Israel
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 09期
关键词：
D O I：
10.1021/ol0157454
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] Addition of "zirconocene" to 1-alkynylphosphonates gives three-membered zirconacylces that can be hydrolyzed to cis-vinylphosphonates or further reacted with alkynes/hydrolysis to give substituted (Z,E)- and (E,E)-1,3-butadienylphosphonates.
引用
收藏
页码：1379 / 1381
页数：3
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