Synthesis, characterization and catalytic properties of tetrachlorocuprate(II) immobilized on layered double hydroxide

被引：9
作者：
Amini, Mojtaba [1 ]
Nikkhoo, Mohammad [1 ,2 ]
Farnia, S. Morteza F. [2 ]
机构：
[1] Univ Maragheh, Dept Chem, Fac Sci, Maragheh, Iran
[2] Univ Tehran, Dept Chem, Tehran, Iran
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2017年 / 31卷 / 09期
关键词：
azide-alkyne cycloaddition; copper; layered double hydroxide; ANIONIC CLAYS; CLICK CHEMISTRY; CYCLOADDITION; COPPER; NANOPARTICLES; AZIDES; REACTIVITY; COMPLEXES; OXIDATION; ALKYNES;
D O I：
10.1002/aoc.3710
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Readily prepared copper(II) immobilized on layered double hydroxide has been found to effectively catalyse the 1,3-dipolar cycloaddition (CuAAC) of a variety terminal alkynes and benzyl azides generated in situ from sodium azide and benzyl halides furnishing the corresponding 1,2,3-triazoles in excellent yields. The advantages of the protocol are short reaction time, mild reaction conditions, reusability of the catalyst and applicability to a wide range of substrates.
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页数：5
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共 40 条
[1]   Cube-octameric silsesquioxane-mediated cargo copper Schiff base for efficient click reaction in aqueous media [J].
Akbari, Ali ;
Arsalani, Nasser ;
Amini, Mojtaba ;
Jabbari, Esmaiel .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 414 :47-54
[2]   Copper nanoparticles supported on CeO2 as an efficient catalyst for click reactions of azides with alkynes [J].
Amini, Mojtaba ;
Hassandoost, Ramin ;
Bagherzadeh, Mojtaba ;
Gautam, Sanjeev ;
Chae, Keun Hwa .
CATALYSIS COMMUNICATIONS, 2016, 85 :13-16
[3]   Synthesis, structure, and catalytic properties of copper, palladium and cobalt complexes containing an N,O-type bidentate thiazoline ligand [J].
Amini, Mojtaba ;
Bayrami, Arshad ;
Marashi, Mohammad Nazari ;
Arab, Ali ;
Ellern, Arkady ;
Woo, L. Keith .
INORGANICA CHIMICA ACTA, 2016, 443 :22-27
[4]   An effective heterogeneous L-proline catalyst for the asymmetric aldol reaction using anionic clays as intercalated support [J].
An, Zhe ;
Zhang, Wenhui ;
Shi, Huimin ;
He, Jing .
JOURNAL OF CATALYSIS, 2006, 241 (02) :319-327
[5]   HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].
Cavani, F. ;
Trifiro, F. ;
Vaccari, A. .
CATALYSIS TODAY, 1991, 11 (02) :173-301
[6]   Layered double hydroxide supported nanopalladium catalyst for Heck-, Suzuki-, Sonogashira-, and Stille-type coupling reactions of chloroarenes [J].
Choudary, BM ;
Madhi, S ;
Chowdari, NS ;
Kantam, ML ;
Sreedhar, B .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) :14127-14136
[7]   Transannulation of 1-Sulfonyl-1,2,3-triazoles with Heterocumulenes [J].
Chuprakov, Stepan ;
Kwok, Sen Wai ;
Fokin, Valery V. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (12) :4652-4655
[8]   Adsorption of phosphate by layered double hydroxides in aqueous solutions [J].
Das, J. ;
Patra, B. S. ;
Baliarsingh, N. ;
Parida, K. M. .
APPLIED CLAY SCIENCE, 2006, 32 (3-4) :252-260
[9]   [(NHC)2Cu]X Complexes as Efficient Catalysts for Azide-Alkyne Click Chemistry at Low Catalyst Loadings [J].
Diez-Gonzalez, Silvia ;
Nolan, Steven P. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (46) :8881-8884
[10]   A [(NHC)CuCl] complex as a latent Click catalyst [J].
Diez-Gonzalez, Silvia ;
Stevens, Edwin D. ;
Nolan, Steven P. .
CHEMICAL COMMUNICATIONS, 2008, (39) :4747-4749
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