The performance of ν-support vector regression on determination of soluble solids content of apple by acousto-optic tunable filter near-infrared spectroscopy

被引:24
作者
Zhu, Dazhou
Ji, Baoping
Meng, Chaoying
Shi, Bolin
Tu, Zhenhua
Qing, Zhaoshen
机构
[1] China Agr Univ, Coll Food Sci & Nutr Engn, Beijing 100083, Peoples R China
[2] China Agr Univ, Coll Informat & Elect Engn, Beijing 100083, Peoples R China
关键词
support vector machine; nu-support vector regression; apple; soluble solids content; near-infrared spectroscopy;
D O I
10.1016/j.aca.2007.07.047
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The nu-support vector regression (nu-SVR) was used to construct the calibration model between soluble solids content (SSc) of apples and acousto-optic tunable filter near-infrared (AOTF-NIR) spectra. The performance of nu-SVR was compared with the partial least square regression (PLSR) and the back-propagation artificial neural networks (BP-ANN). The influence of SVR parameters on the predictive ability of model was investigated. The results indicated that the parameter nu had a rather wide optimal area (between 0.35 and 1 for the apple data). Therefore, we could determine the value of v beforehand and focus on the selection of other SVR parameters. For analyzing SSC of apple, nu-SVR was superior to PLSR and BP-ANN, especially in the case of fewer samples and treating the noise polluted spectra. Proper spectra pretreatment methods, such as scaling, mean center, standard normal variate (SNV) and the wavelength selection methods (stepwise multiple linear regression and genetic algorithm with PLS as its objective function), could improve the quality of nu-SVR model greatly. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:227 / 234
页数:8
相关论文
共 31 条
[21]   Multivariate calibration with least-squares support vector machines [J].
Thissen, U ;
Üstün, B ;
Melssen, WJ ;
Buydens, LMC .
ANALYTICAL CHEMISTRY, 2004, 76 (11) :3099-3105
[22]   Determination of optimal support vector regression parameters by genetic algorithms and simplex optimization [J].
Üstün, B ;
Melssen, WJ ;
Oudenhuijzen, M ;
Buydens, LMC .
ANALYTICA CHIMICA ACTA, 2005, 544 (1-2) :292-305
[23]   Benchmarking least squares support vector machine classifiers [J].
van Gestel, T ;
Suykens, JAK ;
Baesens, B ;
Viaene, S ;
Vanthienen, J ;
Dedene, G ;
de Moor, B ;
Vandewalle, J .
MACHINE LEARNING, 2004, 54 (01) :5-32
[24]  
Vapnik V. N., 1998, Statistical learning theory, V1, DOI DOI 10.1007/978-1-4419-1428-6_5864
[25]   Non-destructive determination of soluble solids in apple fruit by near infrared spectroscopy (NIRS) [J].
Ventura, M ;
de Jager, A ;
de Putter, H ;
Roelofs, FPMM .
POSTHARVEST BIOLOGY AND TECHNOLOGY, 1998, 14 (01) :21-27
[26]   The radial basis functions - Partial least squares approach as a flexible non-linear regression technique [J].
Walczak, B ;
Massart, DL .
ANALYTICA CHIMICA ACTA, 1996, 331 (03) :177-185
[27]   Fast qualitative analysis of textile fiber in near infrared spectroscopy based on support vector machine [J].
Wang, DH ;
Jin, SZ ;
Gan, B ;
Feng, HX .
2ND INTERNATIONAL CONFERENCE ON ADVANCED OPTICAL MANUFACTURING AND TESTING TECHNOLOGIES: ADVANCED OPTICAL MANUFACTURING TECHNOLOGIES, 2006, 6149
[28]  
WANG HW, 1999, METHOD ITS APPL PART
[29]   Comparison of principal components regression and partial least squares regression through generic simulations of complex mixtures [J].
Wentzell, PD ;
Montoto, LV .
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 2003, 65 (02) :257-279
[30]  
YING Y, 2005, P SOC PHOTO-OPT INS, V5996