On the calculation of diffusion coefficients and aggregation numbers of nonionic surfactants in micellar solutions

被引：4
|
作者：
Rusanov, A. I. [1 ,2 ]
Movchan, T. G. [1 ]
Plotnikova, E. V. [1 ]
机构：
[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia
[2] St Petersburg State Univ, Mendeleev Ctr, St Petersburg 199034, Russia
来源：
COLLOID JOURNAL | 2017年 / 79卷 / 05期
基金：
俄罗斯科学基金会;
关键词：
DYNAMIC LIGHT-SCATTERING; AQUEOUS-SOLUTIONS; MICELLIZATION; HYDRATION; EXCHANGE; ETHER;
D O I：
10.1134/S1061933X17050118
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The calculation of the diffusion coefficients of nonionic surfactants as functions of their concentrations in micellar solutions has been analyzed within the framework of the quasi-chemical version of the law of mass action. The methods of the introduction of initial calculation parameters, calculation scheme for an ideal mixture of monomeric molecules and micelles, and corrections for varying solution viscosity have been considered. Numerical estimations have been performed using aqueous tetraoxyethylene octyl ether, pentaoxyethylene hexyl ether, and octyl-beta-D-glucopyranoside solutions as examples.
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页码：661 / 667
页数：7
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