Rhodium catalysed hydroformylation using diphenylphosphine functionalised carbosilane dendrimers

被引：40

作者：

de Groot, D ^{[1
]}

Emmerink, PG ^{[1
]}

Coucke, C ^{[1
]}

Reek, JNH ^{[1
]}

Kamer, PCJ ^{[1
]}

van Leeuwen, PWNM ^{[1
]}

机构：

[1] Univ Amsterdam, Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 12期

关键词：

carbosilane dendrimers; hydroformylation; phosphines; rhodium; catalysis;

D O I：

10.1016/S1387-7003(00)00168-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diphenylphosphine functionalised carbosilane dendrimers Si((CH2)(n)Si(CH3)(2)(CH2PPh2))(4) (n=2,3; generation 1-3) and Si((CH2)(n)Si(CH3)(CH2PPh2)(2))(4) (n = 2,3; generation 1-2) have been synthesised and used as ligands in the rhodium catalysed hydroformylation of 1-octene. The activity of the system depends on the size and flexibility of the dendrimeric ligand. (C) 2000 Published by Elsevier Science S.A.

引用

页码：711 / 713

页数：3

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