Fabrication of the silver/polypyrrole/polyacrylonitrile composite nanofibrous mats

被引:37
作者
Chen, Rui [1 ]
Zhao, Shizhen [1 ]
Han, Gaoyi [1 ]
Dong, Jianhua [1 ]
机构
[1] Shanxi Univ, Educ Minist, Key Lab Chem Biol & Mol Engn, Inst Mol Sci, Taiyuan 030006, Peoples R China
基金
中国国家自然科学基金;
关键词
electrospinning; polypyrrole; silver; polyacrylonitrile;
D O I
10.1016/j.matlet.2008.05.054
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The AgNO3/polyacrylonitrile hybrid nanofibers were prepared by using electrospinning technique, then the hybrid fibers of AgNO3/polyacrylonitrile were treated with pyrrole in the boiling toluene medium, finally, the silver/polypyrrole/polyacrylonitrile composite fibrous mats were obtained. The scanning electron microscopy, transmission electron microscopy, X-ray diffraction and Raman spectra were used to characterize the obtained silver/polypyrrole/polyacrylonitrile composite fibrous mats. And the results indicated that the morphologies of the composite fibers were influenced by the content of AgNO3 in the AgNO3/polyacrylonitrile fibers. The silver/polypyrrole composite dispersed in the fibrous mats exhibited core-shell structure, and the conductivity of the optimum silver/polypyrrole/polyacrylonitrile composite fibrous mats is relatively high. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:4031 / 4034
页数:4
相关论文
共 24 条
[1]   Chemical synthesis of polypyrrole: structure-properties relationship [J].
Duchet, J ;
Legras, R ;
Demoustier-Champagne, S .
SYNTHETIC METALS, 1998, 98 (02) :113-122
[2]   High electroactivity of polyaniline in supercapacitors by using a hierarchically porous carbon monolith as a support [J].
Fan, Li-Zhen ;
Hu, Yong-Sheng ;
Maier, Joachim ;
Adelhelm, Philipp ;
Smarsly, Bernd ;
Antonietti, Markus .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (16) :3083-3087
[3]   An investigation of polypyrrole-LiV3O8 composite cathode materials for lithium-ion batteries [J].
Feng, C. Q. ;
Chew, S. Y. ;
Guo, Z. P. ;
Wang, J. Z. ;
Liu, H. K. .
JOURNAL OF POWER SOURCES, 2007, 174 (02) :1095-1099
[4]   One-step synthesis of polypyrrole-coated silver nanocomposite particles and their application as a coloured particulate emulsifier [J].
Fujii, Syuji ;
Aichi, Atsushi ;
Akamatsu, Kensuke ;
Nawafune, Hidemi ;
Nakamura, Yoshinobu .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (36) :3777-3779
[5]   Electromagnetic shielding properties of polypyrrole/polyester composites in the 1-18 GHz frequency range [J].
Hakansson, Eva ;
Amiet, Andrew ;
Kaynak, Akif .
SYNTHETIC METALS, 2006, 156 (14-15) :917-925
[6]   Novel route to pure and composite fibers of polypyrrole [J].
Han, Gaoyi ;
Shi, Gaoquan .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (03) :1490-1494
[7]   Porous polypyrrole/polymethylmethacrylate composite film prepared by vapor deposition polymerization of pyrrole and its application for ammonia detection [J].
Han, Gaoyi ;
Shi, Gaoquan .
THIN SOLID FILMS, 2007, 515 (17) :6986-6991
[8]   Conductive gold films assembled on electrospun poly(methyl methacrylate) fibrous mats [J].
Han, Gaoyi ;
Guo, Bin ;
Zhang, Liwei ;
Yang, Binsheng .
ADVANCED MATERIALS, 2006, 18 (13) :1709-+
[9]   Electrochemical actuator based on single-layer polypyrrole film [J].
Han, GY ;
Shi, GQ .
SENSORS AND ACTUATORS B-CHEMICAL, 2006, 113 (01) :259-264
[10]   Electrochemical growth of aligned N-chiral alkyl substituted polypyrrole micro-ribbons [J].
Han, GY ;
Shi, GQ ;
Yuan, JY ;
Chen, F .
JOURNAL OF MATERIALS SCIENCE, 2004, 39 (14) :4451-4457