The Cyanamide Moiety, Synthesis and Reactivity

被引：79

作者：

Larraufie, Marie-Helene ^{[1
]}

Maestri, Giovanni ^{[1
]}

Malacria, Max ^{[1
]}

Ollivier, Cyril ^{[1
]}

Fensterbank, Louis ^{[1
]}

Lacote, Emmanuel ^{[2
]}

机构：

[1] Univ Paris 06, Inst Parisien Chim Mol, UMR CNRS 7201, F-75005 Paris, France

[2] ICSN CNRS, F-91198 Gif Sur Yvette, France

来源：

SYNTHESIS-STUTTGART | 2012年 / 44卷 / 09期

关键词：

cyanamide; cyanation; nitrogen; heterocycles; nitrogen ligands; ONE-POT SYNTHESIS; CATALYZED 2+2+2 CYCLOADDITION; ONE-FLASK TRANSFORMATION; RUTHENIUM(II) COMPLEXES; EFFICIENT SYNTHESIS; ALLYL CYANAMIDES; DERIVATIVES; NITRILES; ISOTHIOCYANATES; CYCLIZATION;

D O I：

10.1055/s-0031-1289749

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cyanamide moiety provides many opportunities as a building block for the synthesis of nitrogen-containing heterocycles. This review discusses the reported methods for the preparation of alkyl-and N-acylcyanamides and illustrates their reactivity vis-a-vis nucleophilic additions, cycloadditions, radical chemistry and coordination chemistry.

引用

页码：1279 / 1292

页数：14

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