Frequency-dependent electrical conductivity of concentrated dispersions of spherical colloidal particles

被引：15

作者：

Bradshaw-Hajek, B. H. ^{[1
,2
]}

Miklavcic, S. J. ^{[1
,2
]}

White, L. R. ^{[3
]}

机构：

[1] Univ S Australia, Sch Math & Stat, Mawson Lakes, SA 5095, Australia

[2] Linkoping Univ, Dept Sci & Technol, S-60174 Norrkoping, Sweden

[3] Carnegie Mellon Univ, Dept Chem Engn, Pittsburgh, PA 15213 USA

来源：

LANGMUIR | 2008年 / 24卷 / 09期

关键词：

D O I：

10.1021/la703777g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper outlines the application of a self-consistent cell-model theory of electrokinetics to the problem of determining the electrical conductivity of a dense suspension of spherical colloidal particles. Numerical solutions of the standard electrokinetic equations, subject to self-consistent boundary conditions, are implemented in formulas for the electrical conductivity appropriate to the particle-averaged cell model of the suspension. Results of calculations as a function of frequency, zeta potential, volume fraction, and electrolyte composition, are presented and discussed.

引用

页码：4512 / 4522

页数：11

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