Sonochemical synthesis of a nano-structured zinc(II) amidic pillar metal-organic framework

被引：33
作者：
Bigdeli, Mina [1 ]
Morsali, Ali [1 ]
机构：
[1] Tarbiat Modares Univ, Dept Chem, Fac Sci, Tehran, Iran
来源：
ULTRASONICS SONOCHEMISTRY | 2015年 / 27卷
关键词：
Metal-organic framework; Sonochemical; Amidic pillar; Nano-structure; COORDINATION POLYMER PRECURSOR; HYDROGEN; NANOSTRUCTURES; FABRICATION; ADSORPTION; NANOCRYSTALS; COMPLEXES;
D O I：
10.1016/j.ultsonch.2015.05.034
中图分类号：
O42 [声学];
学科分类号：
070206 ; 082403 ;
摘要：
A facile and environmentally friendly nano-scale synthesis of a Zn(II) metal-organic framework (MOP), {[Zn-4(BDC)(4)(bpta)(4)]center dot 5DMF center dot 3H(2)O}(n) (1) (bpta = N,N'-bis(4-pyridinyl)-1,4-benzenedicarboxamide, BDC = 1,4-dicarboxylate, DMF = N,N-dimethylformamide), with nanorods morphology under ultrasonic irradiation at ambient temperature and atmospheric pressure has been explored. This MOF has been characterized by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and IR spectroscopy. Some parameters such as concentration of initial reagents, power ultrasound irradiation and time effects on size and morphology of nano-structured compound 1 have been studied. (C) 2015 Elsevier B.V. All rights reserved.
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页码：416 / 422
页数：7
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