The absolute proton affinity for isobutene

被引：0
|
作者：
Traeger, JC
机构：
[1] School of Chemistry, La Trobe University, Bundoora
来源：
RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 1996年 / 10卷 / 01期
关键词：
D O I：
10.1002/(SICI)1097-0231(19960115)10:1<119::AID-RCM418>3.0.CO;2-O
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Threshold photoionization mass spectrometry has been used to measure the appearance energies for the formation of C4H9+ from isobutane, neopentane and tert-butyl iodide. From the value of 10.821+/-0.008 eV for isobutane, a 298 K heat of formation for the tert-butyl cation of 711.4+/-1.1 kJ mol(-1) is derived, which leads to an absolute proton affinity for isobutene of 801.7+/-1.4 kJ mol(-1).
引用
收藏
页码：119 / 122
页数：4
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