Preparation and Luminescence Properties of Ho3+-Yb3+ Co-doped Phosphate Glass-Ceramics

被引:1
作者
Zhao Meng-Jie [1 ]
Zou Xiang-Yu [1 ]
Xia Yu-Hang [1 ]
Jia Wen-Tao [1 ]
Zhang Hong-Bo [1 ]
Shao Jing [1 ]
Su Chun-Hui [1 ,2 ]
机构
[1] Changchun Univ Sci & Technol, Sch Mat Sci & Engn, Changchun 130022, Jilin, Peoples R China
[2] Changchun Normal Univ, Changchun 130032, Jilin, Peoples R China
关键词
glass-ceramics; phosphate; Ho3+-Yb3+ co-doped; luminescence; quantum efficiency; UP-CONVERSION LUMINESCENCE; NANOCRYSTALS; EMISSION; IONS;
D O I
10.11862/CJIC.2019.007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The Na2O-Y2O3-P2O5-SiO2 precursor glass was prepared by traditional melting method. The transparent phosphate glass-ceramic was successfully synthesized by heat treatment of the precursor glass sample. XRD patterns of glass-ceramics samples were carried out to determine the precipitation of Na36Y18(PO4)(3) crystals in the glass matrix. The effect of heat treatment time on the crystallinity and grain size of glass ceramics were discussed. The heat treatment temperature was 655 degrees C and the heat treatment time was 2 h. By comparing the up-conversion luminescence intensity of Ho3+ doped glass-ceramics with that of Ho3(+)-Yb3+ co-doped glass-ceramics, the optimum doping molar ratio of Ho3+ to Yb3+ was determined to be 1:2. At the same time, the energy transfer between Ho3+-Yb3+ was discussed. The up-conversion luminescence quantum efficiency of the samples were measured by integrating sphere.
引用
收藏
页码:95 / 100
页数:6
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