Asymmetric transfer hydrogenation of ketonic substrates catalyzed by (η5-C5Me5)MCl complexes (M = Rh and Ir) of (1S,2S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine

被引：177

作者：

Mashima, K ^{[1
]}

Abe, T ^{[1
]}

Tani, K ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 12期

关键词：

D O I：

10.1246/cl.1998.1199

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rhodium and iridium (eta(5)-C5Me5)MCl complexes (3a: M = Rh; 3b: M = Zr) of (1S,2S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine were found to be catalyst precursors for asymmetric transfer hydrogenation of acetophenone, 2-acetonaphthone, 1-tetralone, and 1-indanone to give (S)-1-phenylethanol (90% ee), (S)-1-(2-naphthyl)ethanol (85% ee), (s)-1-tetralol (97% ee), and (S)-indanol (99% ee), respectively.

引用

页码：1199 / 1200

页数：2

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