Synthesis and characterization of novel metal-free and metallophthalocyanines diazadioxamacrocycles

被引：17
作者：
Bilgin, A
Ertem, B
Gök, Y
机构：
[1] Karadeniz Tech Univ, Dept Chem, TR-61080 Trabzon, Turkey
[2] Kocaeli Univ, Fac Educ, TR-41300 Kocaeli, Turkey
来源：
SUPRAMOLECULAR CHEMISTRY | 2005年 / 17卷 / 04期
关键词：
phthalocyanine; diazadioxamacrocycle; template effect; macrocyclization; tosylation;
D O I：
10.1080/10610270500054051
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New metal-free phthalocyanines fused in peripheral positions with eight N-monotosylated diaza-12-crown-4 macrocyclic moieties connected by diethylenethio groups have been synthesized by cyclotetramerization of a newly synthesized dicyano-substituted macrocycle. Metallophthalocyanines were also prepared by reaction of the dicyano-substituted macrocycle in the presence of corresponding metal salts and a strong organic base. The new compounds were characterized by a combination of elemental analysis, H-1 and C-13 NMR, IR, electronic and mass spectroscopies.
引用
收藏
页码：277 / 281
页数：5
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