Barrier scattering with complex-valued quantum trajectories: Taxonomy and analysis of isochrones

被引:15
作者
David, Julianne K. [1 ]
Wyatt, Robert E.
机构
[1] Univ Texas Austin, Inst Theoret Chem, Austin, TX 78712 USA
关键词
D O I
10.1063/1.2834223
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
To facilitate the search for isochrones when using complex-valued trajectory methods for quantum barrier scattering calculations, the structure and shape of isochrones in the complex plane were studied. Isochrone segments were categorized based on their distinguishing features, which are shared by each situation studied: High and low energy wave packets, scattering from both thick and thin Gaussian and Eckart barriers of varying height. The characteristic shape of the isochrone is a trifurcated system: Trajectories that transmit the barrier are launched from the lower branch (T), while the middle and upper branches form the segments for reflected trajectories (F and B). In addition, a model is presented for the curved section of the lower branch (from which transmitted trajectories are launched), and important features of the complex extension of the initial wave packet are identified. (c) 2008 American Institute of Physics.
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页数:9
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