Hierarchical FeCo@MoS2 Nanoflowers with Strong Electromagnetic Wave Absorption and Broad Bandwidth

被引:92
作者
Zhou, Chenhui [1 ]
Wu, Chen [1 ]
Yan, Mi [1 ]
机构
[1] Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
FeCo@MoS2 composites; hierarchical nanoflowers; electromagnetic wave absorption; effective bandwidth; impedance matching; ENHANCED MICROWAVE-ABSORPTION; REDUCED GRAPHENE OXIDE; IN-SITU GROWTH; MOS2; NANOSHEETS; MAGNETIC-PROPERTIES; ANODE MATERIALS; LIGHTWEIGHT; COMPOSITES; EXCELLENT; EFFICIENT;
D O I
10.1021/acsanm.8b01203
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Advanced electromagnetic (EM) wave absorbing materials are technologically important with extensively increasing utilization of EM waves in the gigahertz range. Hierarchical structure containing FeCo nanoparticles composited with MoS2 nanoflowers was developed as an effective EM wave absorber. Large surface area and sufficient voids provided by the MoS2 nanoflowers enable uniformly dispersed FeCo nanoparticles with single domain size for enhanced permeability and natural resonance. Existence of the large amount of the FeCo/MoS2 interfaces also improves the dielectric loss. The composite not only exhibits satisfactory impedance matching over a wide frequency range but also provides synergistic effect between magnetic and dielectric loss for effective dissipation of the wave energy. Excellent wave absorption performance was achieved for the composite with a maximum reflection loss (RL) of -64.64 dB at 14.4 GHz and a broad effective absorption bandwidth (RL < -10 dB) of 7.2 GHz at a small thickness of 2 mm. Consequently, a novel type of high-performance wave absorber was developed, and insights for the design of advanced EM wave absorbers with strong absorption capacity and broad effective bandwidth were provided.
引用
收藏
页码:5179 / 5187
页数:17
相关论文
共 62 条
[1]   2D metal carbides and nitrides (MXenes) for energy storage [J].
Anasori, Babak ;
Lukatskaya, Maria R. ;
Gogotsi, Yury .
NATURE REVIEWS MATERIALS, 2017, 2 (02)
[2]   Tuning the Shape Anisotropy and Electromagnetic Screening Ability of Ultrahigh Magnetic Polymer and Surfactant-Capped FeCo Nanorods and Nanocubes in Soft Conducting Composites [J].
Arief, Injamamul ;
Biswas, Sourav ;
Bose, Suryasarathi .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (39) :26285-26297
[3]   Hexagonal and cubic Ni nanocrystals grown on graphene: phase-controlled synthesis, characterization and their enhanced microwave absorption properties [J].
Chen, Tingting ;
Deng, Fang ;
Zhu, Jia ;
Chen, Caifeng ;
Sun, Genban ;
Ma, Shulan ;
Yang, Xiaojing .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (30) :15190-15197
[4]   Characterization and microwave resonance in nanocrystalline FeCoNi flake composite [J].
Deng, L. J. ;
Zhou, P. H. ;
Xie, J. L. ;
Zhang, L. .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (10)
[5]   Photoluminescence from Chemically Exfoliated MoS2 [J].
Eda, Goki ;
Yamaguchi, Hisato ;
Voiry, Damien ;
Fujita, Takeshi ;
Chen, Mingwei ;
Chhowalla, Manish .
NANO LETTERS, 2011, 11 (12) :5111-5116
[6]   Enhanced microwave absorption of flower-like FeNi@C nanocomposites by dual dielectric relaxation and multiple magnetic resonance [J].
Feng, Chao ;
Liu, Xianguo ;
Sun, YuPing ;
Jin, Chuangui ;
Lv, Yaohui .
RSC ADVANCES, 2014, 4 (43) :22710-22715
[7]   A Bottom-Up Approach to Build 3D Architectures from Nanosheets for Superior Lithium Storage [J].
Gong, Yongji ;
Yang, Shubin ;
Zhan, Liang ;
Ma, Lulu ;
Vajtai, Robert ;
Ajayan, Pulickel M. .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (01) :125-130
[8]   The effect of particle size on the characteristics of FeCo nanoparticles [J].
Hesani, M. ;
Yazdani, A. ;
Ravan, B. Abedi ;
Ghazanfari, M. .
SOLID STATE COMMUNICATIONS, 2010, 150 (13-14) :594-597
[9]   Magnetic Behavior, Electromagnetic Multiresonances, and Microwave Absorption of the Interfacial Engineered Fe@FeSi/SiO2 Nanocomposite [J].
Javid, Muhammad ;
Zhou, Yuanliang ;
Wang, Dongxing ;
Li, Da ;
Shi, Guimei ;
Kim, Unchol ;
Zhou, Lei ;
Dong, Xinglong ;
Zhang, Zhidong .
ACS APPLIED NANO MATERIALS, 2018, 1 (03) :1309-1320
[10]   Solvothermal synthesis of CoxFe3-xO4 spheres and their microwave absorption properties [J].
Ji, Renlong ;
Cao, Chuanbao ;
Chen, Zhuo ;
Zhai, Huazhang ;
Bai, Ju .
JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (29) :5944-5953