Preparation of self-assembled mercaptoalkanoic acid multilayers on GaAs (110) surfaces

被引：13
作者：
Ohno, H
Nagahara, LA
Mizutani, W
Takagi, J
Tokumoto, H
机构：
[1] Sharp Co Ltd, Corp Res & Dev Grp, Adv Technol Res Labs, Tenri, Nara 6328567, Japan
[2] Motorola Inc, Phoenix Corp Res Labs, Tempe, AZ 85284 USA
[3] Natl Inst Adv Interdisciplinary Res, Joint Res Ctr Atom Technol, Tsukuba, Ibaraki 3058562, Japan
来源：
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1999年 / 38卷 / 1A期
关键词：
self-assembled multilayer; 16-mercaptohexadecanoic acid; GaAs (110); copper acetate; ionic interaction; atomic force microscopy; X-ray photoelectron spectroscopy; infrared spectroscopy; Auger electron spectroscopy;
D O I：
10.1143/JJAP.38.180
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Mono- and double layer films have been formed by the self-assembly of 16-mercapto-hexadecanoic acid, (MHDA), HS(CH2)(15)COOH, via selective ionic interaction. To understand the formation process in the nanometer length scale, atomic force microscopy (AFM) studies have been conducted in combination with micro X-ray photoelectron spectroscopy (mu-XPS), Auger electron spectroscopy (AES) and-micro-fourier transform infrared spectroscopy with the attenuated total reflection method (mu-FTIR ATR). After the formation of a self-assembled monolayer (SAM) was completed,. the surface treated with copper ions was immersed in a solution of MHDA. By this method, an atomically smooth double layer was successfully formed on cleaved GaAs (110)surfaces. The formation speed of the second layer was faster Wan that of the SAM, indicating stronger interaction of thiol functional groups with Cu2+ ions than with GaAs surfaces.
引用
收藏
页码：180 / 185
页数：6
相关论文
共 16 条
  • [1] GROWTH-STRUCTURE OF CHEMISORBED OXYGEN ON GAAS(110) AND INP(110) SURFACES
    BERTNESS, KA
    YEH, JJ
    FRIEDMAN, DJ
    MAHOWALD, PH
    WAHI, AK
    KENDELEWICZ, T
    LINDAU, I
    SPICER, WE
    [J]. PHYSICAL REVIEW B, 1988, 38 (08) : 5406 - 5421
  • [2] THEORY OF THE OXIDATION OF METALS
    CABRERA, N
    MOTT, NF
    [J]. REPORTS ON PROGRESS IN PHYSICS, 1948, 12 : 163 - 184
  • [3] SELF-ASSEMBLED MULTILAYERS OF OMEGA-MERCAPTOALKANOIC ACIDS - SELECTIVE IONIC INTERACTIONS
    EVANS, SD
    ULMAN, A
    GOPPERTBERARDUCCI, KE
    GERENSER, LJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) : 5866 - 5868
  • [4] ELECTRONIC STATES OF METAL ATOMS ON THE GAAS(110) SURFACE STUDIED BY SCANNING TUNNELING MICROSCOPY
    FEENSTRA, RM
    [J]. PHYSICAL REVIEW LETTERS, 1989, 63 (13) : 1412 - 1415
  • [5] XPS STUDIES OF SELF-ASSEMBLED MULTILAYER FILMS
    FREEMAN, TL
    EVANS, SD
    ULMAN, A
    [J]. LANGMUIR, 1995, 11 (11) : 4411 - 4417
  • [6] Harkins WD, 1942, J CHEM PHYS, V10, P268, DOI 10.1063/1.1723719
  • [7] ADSORPTION OF ORDERED ZIRCONIUM PHOSPHONATE MULTILAYER FILMS ON SILICON AND GOLD SURFACES
    LEE, H
    KEPLEY, LJ
    HONG, HG
    AKHTER, S
    MALLOUK, TE
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (09) : 2597 - 2601
  • [8] ON THE OXIDATION OF III-V COMPOUND SEMICONDUCTORS
    MONCH, W
    [J]. SURFACE SCIENCE, 1986, 168 (1-3) : 577 - 593
  • [9] FUNDAMENTAL-STUDIES OF MICROSCOPIC WETTING ON ORGANIC-SURFACES .1. FORMATION AND STRUCTURAL CHARACTERIZATION OF A SELF-CONSISTENT SERIES OF POLYFUNCTIONAL ORGANIC MONOLAYERS
    NUZZO, RG
    DUBOIS, LH
    ALLARA, DL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (02) : 558 - 569
  • [10] AFM OBSERVATION OF SELF-ASSEMBLED MONOLAYER FILMS ON GAAS(110)
    OHNO, H
    MOTOMATSU, M
    MIZUTANI, W
    TOKUMOTO, H
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1995, 34 (2B): : 1381 - 1386
12