Conjugated Dienyl Derivatives by Green Bisallylic Substitution: Synthetic and Mechanistic Insight

被引：6

作者：

Cazorla, Clement ^{[1
]}

Billamboz, Muriel ^{[2
]}

Chevrin-Villette, Carole ^{[2
]}

Hapiot, Frederic ^{[3
]}

Monflier, Eric ^{[3
]}

Len, Christophe ^{[1
]}

机构：

[1] Univ Technol Compiegne, Sorbonne Univ, Ctr Rech Royallieu, CS 60319, F-60203 Compiegne, France

[2] Ecole Super Chim Organ & Minerale, 1 Allee Reseau Jean Marie Buckmaster, F-60200 Compiegne, France

[3] Univ Lille, CNRS, Cent Lille, ENSCL,UMR 8181,UCCS,Univ Artois, F-62300 Lens, France

来源：

CHEMCATCHEM | 2016年 / 8卷 / 14期

关键词：

dienes; green chemistry; mass spectrometry; microwave chemistry; palladium; TSUJI-TROST REACTION; PALLADIUM; WATER; ELECTROSPRAY; IONIZATION; SURFACTANT; CATALYST;

D O I：

10.1002/cctc.201600343

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first palladium-catalyzed bisallylic substitution on biobased bisallylic derivatives was explored. The developed method, performed under green conditions with microwave irradiation, led to valuable conjugated dienes. The mechanism was studied by ESI-MS and NMR spectroscopy, which highlighted the involvement of bis-p-allylpalladium complexes in the catalytic cycle.

引用

页码：2321 / 2328

页数：8

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