Two types of rhodium-catalyzed CS/CS metathesis reactions: formation of CS/CS bonds and CC/SS bonds

被引：10

作者：

Arisawa, Mieko ^{[1
]}

Tagami, Yoko ^{[1
]}

Yamaguchi, Masahiko ^{[1
,2
]}

机构：

[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, WPI Adv Inst Mat Res, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 10期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/j.tetlet.2008.01.040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rhodium complex catalyzes two types of single bond metathesis reactions of two CS bonds depending on the added ligand: CS/CS to CS/CS metathesis and CS/CS to CC/SS metathesis. In the presence of a catalytic amount of RhH(PPh3)(4) and 1,1 '-bis(diphenylphosphino)ferrocene (dppf), two 1-alkylthioalkynes exchange alkylthio groups to give equilibrium mixtures of four 1-alkylthioalkynes. When tris(p-methoxyphenyl)phosphine or diphenylmethylphosphine is used, 1,3-butadiynes are obtained. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1593 / 1597

页数：5

共 17 条

[1] RhCl3-catalyzed disulfide exchange reaction using water solvent in homogeneous and heterogeneous systems
Arisawa, M
Suwa, A
Yamaguchi, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (06) : 1159 - 1168
[2] Equilibrating C-S bond formation by C-H and S-S bond metathesis. Rhodium-catalyzed alkylthiolation reaction of 1-alkynes with disulfides
Arisawa, M
Fujimoto, K
Morinaka, S
Yamaguchi, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (35) : 12226 - 12227
[3] Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides
Arisawa, M
Ono, T
Yamaguchi, M
[J]. TETRAHEDRON LETTERS, 2005, 46 (34) : 5669 - 5671
[4] Oxidation/reduction interconversion of thiols and disulfides using hydrogen and oxygen catalyzed by a rhodium complex
Arisawa, M
Sugata, C
Yamaguchi, M
[J]. TETRAHEDRON LETTERS, 2005, 46 (36) : 6097 - 6099
[5] Rhodium-catalyzed sulfur atom exchange reaction between organic polysulfides and sulfur
Arisawa, M
Tanaka, K
Yamaguchi, M
[J]. TETRAHEDRON LETTERS, 2005, 46 (28) : 4797 - 4800
[6] Rhodium-catalyzed disulfide exchange reaction
Arisawa, M
Yamaguchi, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (22) : 6624 - 6625
[7] ARISAWA M, IN PRESS PURE APPL C
[8] ARISAWA M, 2007, SYNTH ORG CHEM JPN, V65, P1213
[9] AYE KT, 1989, ORGANOMETALLICS, V8, P1518
[10] SYNTHESIS AND STUDY OF THE BENZYLPALLADIUM(IV) AND NAPHTHYLPALLADIUM(IV) COMPLEXES PDBRME2(CH2AR) (BPY2), PDBRME2(CH2AR) (PHEN2) AND MU-HYDROCARBYL PALLADIUM(IV)-PALLADIUM(IV) AND PALLADIUM(IV) PLATINUM(IV) COMPLEXES AND THE STRUCTURE OF FAC-PDBRME2(CH2-P-C6H4BR) (PHEN)
BYERS, PK
CANTY, AJ
SKELTON, BW
TRAILL, PR
WATSON, AA
WHITE, AH
[J]. ORGANOMETALLICS, 1990, 9 (12) : 3080 - 3085

← 1 2 →