Selective functionalization of methylene bridges of calix[6]arenes. Isolation and identification of stable conformers of methyl ether of p-tert-butylcalix[6]arene

被引：5

作者：

Arora, Shafali ^{[1
]}

Sharma, Shivali ^{[1
]}

Mithu, Venus S. ^{[1
]}

Hee-Lee, Chang ^{[2
]}

Singh, Kamaljit ^{[1
]}

机构：

[1] Guru Nanak Dev Univ, UGC Ctr Adv Study 1, Dept Chem, Amritsar 143005, Punjab, India

[2] Kangwoon Natl Univ, Dept Chem, Chunchon 200701, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 20期

基金：

新加坡国家研究基金会;

关键词：

TRANS-ALKYL SUBSTITUENTS; CONFORMATIONAL-ANALYSIS; MOLECULAR RECOGNITION; METAL-BINDING; CALIXARENES; DERIVATIVES; ROUTE;

D O I：

10.1039/c4cc10400e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct disubstitution at the methylene bridges of p-tert-butylcalix[6] arenemethyl ether has been achieved for the first time using a lithiation-substitution protocol. Two stable conformers have been isolated using column chromatography, and their structures have been unambiguously confirmed from 1D, 2D and variable temperature NMR studies and single crystal X-ray structure analysis.

引用

页码：4227 / 4230

页数：4

共 38 条

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