Microstructure and atomic configuration of the (001)-oriented surface of epitaxial Ni-Mn-Ga thin films

被引:25
作者
Leicht, P. [1 ]
Laptev, A. [1 ]
Fonin, M. [1 ]
Luo, Y. [2 ]
Samwer, K. [2 ]
机构
[1] Univ Konstanz, Fachbereich Phys, D-78457 Constance, Germany
[2] Univ Gottingen, Inst Phys 1, D-37077 Gottingen, Germany
关键词
NI2MNGA SINGLE-CRYSTALS; MARTENSITIC-TRANSFORMATION; ALLOYS; PHASE; MICROSCOPY;
D O I
10.1088/1367-2630/13/3/033021
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The (001)-oriented surface of epitaxial off-stoichiometric Ni-Mn-Ga ferromagnetic shape memory alloys was studied in both austenitic and martensitic phases. Scanning tunneling microscopy (STM) imaging of the austenitic surface reveals a well-ordered and reconstruction-free surface exhibiting predominantly Mn-Ga termination. We found that only one of the two atomic species (Ga or Mn) is visible in STM, which is attributed to a pronounced geometric corrugation of the surface layer. After a transformation of the sample from the initial austenitic phase to the martensitic phase upon a high-temperature annealing step, a thorough investigation of the martensitic surface was conducted. On a larger scale, pronounced corrugation lines arise from the macroscopically twinned surface. A second corrugation feature is found on a distinctly smaller scale and is shown to originate from the modulated nature of the martensitic film structure. The irregularly spaced corrugation lines support the model of adaptive martensites.
引用
收藏
页数:14
相关论文
共 26 条
[1]   The crystal structure and phase transitions of the magnetic shape memory compound Ni2MnGa [J].
Brown, PJ ;
Crangle, J ;
Kanomata, T ;
Matsmuoto, M ;
Neumann, KU ;
Ouladdiaf, B ;
Ziebeck, KRA .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (43) :10159-10171
[2]   In situ studies of the martensitic transformation in epitaxial Ni-Mn-Ga films [J].
Buschbeck, J. ;
Niemann, R. ;
Heczko, O. ;
Thomas, M. ;
Schultz, L. ;
Faehler, S. .
ACTA MATERIALIA, 2009, 57 (08) :2516-2526
[3]   Photoemission study of the (100) surface of Ni2MnGa and Mn2NiGa ferromagnetic shape memory alloys [J].
Dhaka, R. S. ;
D'Souza, S. W. ;
Maniraj, M. ;
Chakrabarti, Aparna ;
Schlagel, D. L. ;
Lograsso, T. A. ;
Barman, S. R. .
SURFACE SCIENCE, 2009, 603 (13) :1999-2004
[4]   Modelling the phase diagram of magnetic shape memory Heusler alloys [J].
Entel, P ;
Buchelnikov, VD ;
Khovailo, VV ;
Zayak, AT ;
Adeagbo, WA ;
Gruner, ME ;
Herper, HC ;
Wassermann, EF .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2006, 39 (05) :865-889
[5]  
Fähler S, 2008, ACTUATOR, P754
[6]   Crystal structure and macrotwin interface of five-layered martensite in Ni-Mn-Ga magnetic shape memory alloy [J].
Ge, Y. ;
Jiang, H. ;
Sozinov, A. ;
Soderberg, O. ;
Lanska, N. ;
Keranen, J. ;
Kauppinen, E. I. ;
Lindroos, V. K. ;
Hannula, S. -P. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 438 :961-964
[7]  
Greenwood N. N., 2012, Chemistry of the Elements
[8]   Adaptive Modulations of Martensites [J].
Kaufmann, S. ;
Roessler, U. K. ;
Heczko, O. ;
Wuttig, M. ;
Buschbeck, J. ;
Schultz, L. ;
Faehler, S. .
PHYSICAL REVIEW LETTERS, 2010, 104 (14)
[9]   ADAPTIVE PHASE FORMATION IN MARTENSITIC-TRANSFORMATION [J].
KHACHATURYAN, AG ;
SHAPIRO, SM ;
SEMENOVSKAYA, S .
PHYSICAL REVIEW B, 1991, 43 (13) :10832-10843
[10]   A fabrication technology for epitaxial Ni-Mn-Ga microactuators [J].
Khelfaoui, F. ;
Kohl, M. ;
Buschbeck, J. ;
Heczko, O. ;
Faehler, S. ;
Schultz, L. .
EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS, 2008, 158 (1) :167-172