N-Iodosuccinimide (NIS) Promoted Synthesis of Unsymmetrical Disulfides Starting from Isothiocyanates Under Transition-Metal-Free Conditions

被引：4
|
作者：
Yang, Cheng-Li [1 ]
Xiao, Hua-Qing [1 ,4 ]
Dong, Zhi-Bing [1 ,2 ,3 ,4 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Peoples R China
[2] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
[3] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430205, Peoples R China
[4] Hubei Greenhome Mat Technol INC, Xiantao 433000, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 37期
关键词：
N-Iodosuccinimide (NIS); One-pot; Synthesis; Transition-metal-free; Unsymmetrical disulfides; EFFICIENT SYNTHESIS; S-ARYLATION; THIOLS; ACIDS;
D O I：
10.1002/ejoc.202200954
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Under transition-metal-free conditions, a series of unsymmetrical disulfides could be quickly and conveniently obtained by NIS (N-Iodosuccinimide)-promotion in one pot manner. This method features mild conditions, easy operation, short reaction time and wide substrate scopes. It's noteworthy that the desired products could be obtained in moderate to good yields from inexpensive and easily available starting materials, providing an alternative way to afford various unsymmetrical disulfides.
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页数：5
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