Solid-supported stereospecific living Ziegler-Natta polymerization of α-olefins

被引：36

作者：

Zhang, YH ^{[1
]}

Sita, LR ^{[1
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 18期

关键词：

D O I：

10.1039/b307555a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A successful strategy has been developed for the synthesis of a cationic pentamethylcyclopentadienyl zirconium amidinate initiator on a lightly crosslinked polystyrene-divinylbenzene support that can be used to polymerize alpha-olefins in a living and stereospecific fashion.

引用

页码：2358 / 2359

页数：2

共 27 条

[1]

Abbenhuis HCL, 1999, ANGEW CHEM INT EDIT, V38, P1058, DOI 10.1002/(SICI)1521-3773(19990419)38:8<1058::AID-ANIE1058>3.0.CO

[2]

2-8

[3] Synthesis and characterization of a new polymer support for a metallocene catalyst [J].

Barrett, AGM ;

de Miguel, YR .

TETRAHEDRON, 2002, 58 (19) :3785-3792

[4] A well-defined metallocene catalyst supported on polystyrene beads [J].

Barrett, AGM ;

de Miguel, YR .

CHEMICAL COMMUNICATIONS, 1998, (19) :2079-2080

[5] STEREOSPECIFIC OLEFIN POLYMERIZATION WITH CHIRAL METALLOCENE CATALYSTS [J].

BRINTZINGER, HH ;

FISCHER, D ;

MULHAUPT, R ;

RIEGER, B ;

WAYMOUTH, RM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (11) :1143-1170

[6] Polystyrene supports for vanadium ethylene polymerisation catalysts [J].

Chan, MCW ;

Chew, KC ;

Dalby, CI ;

Gibson, VC ;

Kohlmann, A ;

Little, IR ;

Reed, W .

CHEMICAL COMMUNICATIONS, 1998, (16) :1673-1674

[7] Supported metallocene polymerization catalysis [J].

Chien, JCW .

TOPICS IN CATALYSIS, 1999, 7 (1-4) :23-36

[8]

Coates GW, 2002, ANGEW CHEM INT EDIT, V41, P2236, DOI 10.1002/1521-3773(20020703)41:13<2236::AID-ANIE2236>3.0.CO

[9]

2-3

[10] Advances in non-metallocene olefin polymerization catalysis [J].

Gibson, VC ;

Spitzmesser, SK .

CHEMICAL REVIEWS, 2003, 103 (01) :283-315

← 1 2 3 →