Some water-soluble organometallic complexes of group 10 transition metal(II) ions with 1,3,5-triaza-7-phosphaadamantane (TPA).: Syntheses, characterization and reactivity.: The crystal and molecular structure of [Ni(CN)2(TPA)3]•4.3H2O

被引：21

作者：

Alyea, EC ^{[1
]}

Ferguson, G ^{[1
]}

Kannan, S ^{[1
]}

机构：

[1] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada

来源：

POLYHEDRON | 1998年 / 17卷 / 16期

基金：

加拿大自然科学与工程研究理事会;

关键词：

group; 10; complexes; 1,3,5-triaza-7-phosphaadamantane; crystal structure;

D O I：

10.1016/S0277-5387(98)00055-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1,3,5-triaza-7-phosphaadamantane [TPA] complexes of the type [MCl2(TPA)(2)] (where M = Ni, Pd, Pt), [Ni(CN)(2)(TPA)(3)] and [PtCl(TPA)(3)](BPh4) have been synthesized and characterized by H-1, (31)p{H-1} NMR, Laser-Raman spectroscopy and elemental anaIyses; The reactivity of the complexes [MCl2(TPA)(2)] with water to produce the oxide of TPA follows the order Pt > Pd > Ni. The structure of the Complex [Ni(CN)(2)(TPA)(3)]. 4.3H(2)O was determined by single crystal X-ray diffraction methods. The structure deter mination shows that the nickel atom has a trigonal-bipyramidal geometry with the cyanide ligands in the apical positions. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2727 / 2732

页数：6

共 22 条

[1] CORRELATION OF SPECTROSCOPIC PROPERTIES AND CRYSTAL STRUCTURE OF 2 CLOSELY RELATED 5-CO-ORDINATE COMPLEXES OF NICKEL(2) CYANIDE WITH MONODENTATE HETEROCYCLIC PHOSPHINE LIGANDS [J].

ALLEN, DW ;

MANN, FG ;

MILLAR, IT ;

POWELL, HM ;

WATKIN, D .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (17) :1004-&

[2]

ALLEN FH, 1993, CHEM DESIGN AUTOMATI, V8, P131

[3] Syntheses and structures of [Mo(CO)(3)(TPA)(3)] and [Mo(CO)(3)(ETPB)(3)]. A structural and spectroscopic correlation [J].

Alyea, EC ;

Ferguson, G ;

Kannan, S .

POLYHEDRON, 1997, 16 (20) :3533-3537

[4] SYNTHESIS, SOLID-STATE P-31 CP-MAS NMR INFRARED AND RAMAN STUDIES OF MERCURY(II) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (PTA) [J].

ALYEA, EC ;

FISHER, KJ ;

JOHNSON, S .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1989, 67 (08) :1319-1323

[5] Intermolecular hydrogen•••metal interactions.: The crystal structure of {cis-[PdCl2(TPA)2]}2•H2O, a water-soluble palladium(II) tertiary phosphine complex [J].

Alyea, EC ;

Ferguson, G ;

Kannan, S .

CHEMICAL COMMUNICATIONS, 1998, (03) :345-346

[6] A P-31 AND MO-95 NMR-STUDY OF SOME MOLYBDENUM AND TUNGSTEN CARBONYL-COMPLEXES OF A SMALL AIR-STABLE ALIPHATIC PHOSPHINE, 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (PTA) [J].

ALYEA, EC ;

FISHER, KJ ;

FOO, S ;

PHILIP, B .

POLYHEDRON, 1993, 12 (05) :489-492

[7]

ALYEA EC, 1988, 3 CHEM C N AM JUN 5

[8] SYNTHESES, STRUCTURES, AND SPECTROSCOPIC PROPERTIES OF GOLD(I) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (TPA) - CORRELATION OF THE SUPRAMOLECULAR AU...AU INTERACTION AND PHOTOLUMINESCENCE FOR THE SPECIES (TPA)AUCL AND [(TPA-HCL)AUCL] [J].

ASSEFA, Z ;

MCBURNETT, BG ;

STAPLES, RJ ;

FACKLER, JP ;

ASSMANN, B ;

ANGERMAIER, K ;

SCHMIDBAUR, H .

INORGANIC CHEMISTRY, 1995, 34 (01) :75-83

[9] TRANS-DICYANOBIS(1,3,5-TRIAZA-7-PHOSPHAADAMANTANE)PLATINUM(II), [(TPA)(2)PT(CN)(2)] [J].

ASSEFA, Z ;

MCBURNETT, BG ;

STAPLES, RJ ;

FACKLER, JP .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 :1742-1743

[10] SYNTHESIS OF A MONOPHOSPHORUS ANALOG OF HEXAMETHYLENETETRAMINE [J].

DAIGLE, DJ ;

PEPPERMA.AB ;

VAIL, SL .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1974, 11 (03) :407-408

← 1 2 3 →