Biobased 2,5-furandicarboxylic acid (FDCA) and its emerging copolyesters' properties for packaging applications

被引：63
作者：
Pandey, Surabhi [1 ]
Dumont, Marie-Josee [1 ]
Orsat, Valerie [1 ]
Rodrigue, Denis [2 ]
机构：
[1] McGill Univ, Dept Bioresource Engn, 21111 Lakeshore Rd, Ste Anne De Bellevue, PQ H9X 3V9, Canada
[2] Univ Laval, Dept Chem Engn, 1065 Ave Med, Quebec City, PQ G1V 0A6, Canada
来源：
EUROPEAN POLYMER JOURNAL | 2021年 / 160卷
关键词：
Food and beverage packaging; Biodegradability; Poly(butylene adipate-co-furandicarboxylate); Thermomechanical properties; 2; 5-furandicarboxylic acid; SELECTIVE AEROBIC OXIDATION; HYDROXYMETHYLFURFURAL HMF; MECHANICAL-PROPERTIES; FURANDICARBOXYLIC ACID; BARRIER PROPERTIES; DIRECT CONVERSION; FOOD WASTE; POLY(BUTYLENE 2,5-FURANDICARBOXYLATE); BIODEGRADABLE COPOLYESTERS; SUSTAINABLE POLYESTERS;
D O I：
10.1016/j.eurpolymj.2021.110778
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis of 2,5-furandicarboxylic acid (FDCA) based polymers is gaining importance as a replacement for petrochemical polymers due to their excellent thermomechanical and barrier properties. However, the industrial production of FDCA based homopolyesters is impeded due to several factors including poor optical property, low ductility, and slow crystallization rate. In order to tune the properties of FDCA-based homopolyesters, FDCA has been copolymerized with several aliphatic (adipic acid, succinic acid, lactic acid, sebacic acid, polyglycolic acid, and polyethylene glycol) and cyclic (caprolactam and isohexides) comonomers. The present review focuses on the current trends related to the synthesis of FDCA and its copolyesters. The thermomechanical and barrier properties of copolyesters have been discussed concerning applications in the food and beverage packaging sectors, with an emphasis on their biodegradability (hydrolytic and enzymatic) and compostability.
引用
收藏
页数：22
相关论文
共 156 条
[1]   Conversion of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over Au-based catalysts: Optimization of active phase and metal-support interaction [J].
Albonetti, Stefania ;
Lolli, Alice ;
Morandi, Vittorio ;
Migliori, Andrea ;
Lucarelli, Carlo ;
Cavani, Fabrizio .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 163 :520-530
[2]   KINETIC-STUDIES OF THE REACTIONS OF KETOSES AND ALDOSES IN WATER AT HIGH-TEMPERATURE .1. MECHANISM OF FORMATION OF 5-(HYDROXYMETHYL)-2-FURALDEHYDE FROM D-FRUCTOSE AND SUCROSE [J].
ANTAL, MJ ;
MOK, WSL ;
RICHARDS, GN .
CARBOHYDRATE RESEARCH, 1990, 199 (01) :91-109
[3]  
Avantium, 2019, AV ANN REP
[4]  
Boussie T.R., 2013, GOOGLE PATENTS
[5]   Carbon Dioxide Sorption and Transport in Amorphous Poly(ethylene furanoate) [J].
Burgess, Steven K. ;
Kriegel, Robert M. ;
Koros, William J. .
MACROMOLECULES, 2015, 48 (07) :2184-2193
[6]   Water sorption in poly(ethylene furanoate) compared to poly(ethylene terephthalate). Part 2: Kinetic sorption [J].
Burgess, Steven K. ;
Mikkilineni, Dharmik S. ;
Yu, Daniel B. ;
Kim, Danny J. ;
Mubarak, Christopher R. ;
Kriegel, Robert M. ;
Koros, William J. .
POLYMER, 2014, 55 (26) :6870-6882
[7]   Oxygen sorption and transport in amorphous poly(ethylene furanoate) [J].
Burgess, Steven K. ;
Karvan, Oguz ;
Johnson, J. R. ;
Kriegel, Robert M. ;
Koros, William J. .
POLYMER, 2014, 55 (18) :4748-4756
[8]   Chain Mobility, Thermal, and Mechanical Properties of Poly(ethylene furanoate) Compared to Poly(ethylene terephthalate) [J].
Burgess, Steven K. ;
Leisen, Johannes E. ;
Kraftschik, Brian E. ;
Mubarak, Christopher R. ;
Kriegel, Robert M. ;
Koros, William J. .
MACROMOLECULES, 2014, 47 (04) :1383-1391
[9]   Isomannide-Containing Poly(butylene 2,5-furandicarboxylate) Copolyesters via Ring Opening Polymerization [J].
Carlos Morales-Huerta, Juan ;
Martinez de Ilarduya, Antxon ;
Leon, Salvador ;
Munoz-Guerra, Sebastian .
MACROMOLECULES, 2018, 51 (09) :3340-3350
[10]   Blocky poly(-caprolactone-co-butylene 2,5-furandicarboxylate) copolyesters via enzymatic ring opening polymerization [J].
Carlos Morales-Huerta, Juan ;
Martinez de Ilarduya, Antxon ;
Munoz-Guerra, Sebastian .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2018, 56 (03) :290-299
12345678910