Imidazo[1,5-a]pyridine:: A versatile architecture for stable N-heterocyclic carbenes

被引：315

作者：

Alcarazo, M

Roseblade, SJ

Cowley, AR

Fernández, R

Brown, JM

Lassaletta, JM

机构：

[1] CSIC, US, Inst Invest Quim, E-41092 Seville, Spain

[2] Univ Seville, Dept Quim Organ, E-41012 Seville, Spain

[3] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 10期

关键词：

D O I：

10.1021/ja0423769

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The imidazo[1,5-a]pyridine skeleton provides a versatile platform for the generation of new types of stable N-heterocyclic carbenes. Rh(I) mono- (6) and biscarbenes (7) from imidazo[1,5-a]pyridin-3-ylidenes (ImPy) and derivatives such as 13 from a mesoionic carbene were synthesized and characterized. Copyright © 2005 American Chemical Society.

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页码：3290 / 3291

页数：2

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