Carbon foams with high compressive strength derived from mixtures of mesocarbon microbeads and mesophase pitch

被引:129
作者
Li, Sizhong
Song, Yongzhong
Song, Yan [1 ]
Shi, Jingli
Liu, Lang
Wei, Xinghai
Guo, Quangui
机构
[1] Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon MAt, Taiyuan, Peoples R China
[2] Grad Univ Chinese Acad Sci, Beijing 100039, Peoples R China
关键词
D O I
10.1016/j.carbon.2007.05.014
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carbon foam with relatively high compressive strength and suitable thermal conductivity was prepared from mixtures of mesocarbon microbeads (MCMBs) and mesophase pitch, followed by foaming, carbonization and graphitization. The influence of addition amount of MCNIB on the properties of as-prepared carbon foams was investigated in detail. Results showed that addition of MCMBs into mesophase pitch could significantly reduce the amount and length of cracks in carbon foams, which results in increase of compressive strength of carbon foams. Carbon foam with high compressive strength of 23.7 MPa and suitable thermal conductivity of 43.7 W/mK, was obtained by adding 50% MCMBs into mesophase pitch, followed by foaming, carbonization and graphitization. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2092 / 2097
页数:6
相关论文
共 17 条
  • [1] Novel high strength graphitic foams
    Beechem, Thomas
    Lafdi, Khalid
    [J]. CARBON, 2006, 44 (08) : 1548 - 1559
  • [2] PREPARATION OF SYNTACTIC CARBON FOAM
    BENTON, ST
    SCHMITT, CR
    [J]. CARBON, 1972, 10 (02) : 185 - &
  • [3] Self-sinterability of mesocarbon microbeads (MCMB) for preparation of high-density isotropic carbon
    Gao, Y
    Song, HH
    Chen, XH
    [J]. JOURNAL OF MATERIALS SCIENCE, 2003, 38 (10) : 2209 - 2213
  • [4] Anisotropy of mesophase pitch-derived carbon foams
    Ge Min
    Shen Zengmin
    Chi Weidong
    Liu Hui
    [J]. CARBON, 2007, 45 (01) : 141 - 145
  • [5] JIN ZZ, 1996, CHARACTERIZATION MEC, P111
  • [6] Kearns KM, 1999, US Patent, Patent No. 5868974
  • [7] High-thermal-conductivity, mesophase-pitch-derived carbon foams: effect of precursor on structure and properties
    Klett, J
    Hardy, R
    Romine, E
    Walls, C
    Burchell, T
    [J]. CARBON, 2000, 38 (07) : 953 - 973
  • [8] Compressive failure of carbon-foam sandwich composites with holes and/or partial delamination
    Kwon, YW
    Yoon, SH
    Sistare, PJ
    [J]. COMPOSITE STRUCTURES, 1997, 38 (1-4) : 573 - 580
  • [9] Effect of Ti dopant on shrinkage and performance of MCMB-derived carbon laminations
    Liu, Zhan Jun
    Guo, Quan Gui
    Song, Jin Ren
    Liu, Lang
    [J]. CARBON, 2007, 45 (01) : 146 - 151
  • [10] The growth, drainage and breakdown of foams
    Neethling, SJ
    Lee, HT
    Grassia, P
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2005, 263 (1-3) : 184 - 196