Synthesis, Crystal Structure and Thermal Stability of [CuL2(ClO4)2] (L=3-(p-Bromophenyl)-4-(p-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole)

被引：0

作者：

Chen Lang ^{[1
]}

Cheng Hui-Min ^{[1
]}

Jiang Jing-Jing ^{[1
]}

Shen Xuan ^{[1
]}

Zhu Dun-Ru ^{[1
]}

机构：

[1] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 28卷 / 02期

关键词：

Cu(II) complex; crystal structure; 1,2,4-triazole; DINUCLEAR NICKEL(II) COMPLEX; IRON(II) COMPLEXES; MAGNETIC-PROPERTY; TRIARYLTRIAZOLE; MONONUCLEAR;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A copper(II) complex, trans-[CuL2(ClO4)(2)], (L=3-(p-bromophenyl)-4-(p-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole), was synthesized and characterized by FTIR, ESI-MS, TGA/MSC and X-ray crystallography. The complex crystallizes in triclinic system with space group P (1) over bar, a=0.82929(15) rim, b =0.85448(16) rim, c=1.5027(3) nm, alpha=83.517(2)degrees, beta=89.200(2)degrees, gamma=73.064(2)degrees, V=1.011 9(3) nm(3), Z=1 and final R=0.041 2. The copper atom lies in a distorted octahedral environment with two ClO4- ions in the trans positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. The TG analysis shows that the complex is stable below 310 degrees C CCDC: 843042.

引用

页码：381 / 385

页数：5

共 23 条

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