Highly oriented surface-growth and covalent dye labeling of mesoporous metal-organic frameworks

被引：24

作者：

Hinterholzinger, Florian M. ^{[1
,2
]}

Wuttke, Stefan ^{[1
,2
]}

Roy, Pascal ^{[3
]}

Preusse, Thomas ^{[3
]}

Schaate, Andreas ^{[4
]}

Behrens, Peter ^{[4
]}

Godt, Adelheid ^{[3
]}

Bein, Thomas ^{[1
,2
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

[2] Univ Munich, Ctr NanoSci CeNS, D-81377 Munich, Germany

[3] Univ Bielefeld, Dept Chem, D-33615 Bielefeld, Germany

[4] Leibniz Univ Hannover, Inst Inorgan Chem, D-30167 Hannover, Germany

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 14期

关键词：

CHEMISTRY; FILMS;

D O I：

10.1039/c2dt12265k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mesoporous amino-functionalized metal-organic framework thin films with the UiO-68 topology were grown in a highly oriented fashion on two different self-assembled monolayers on gold. The oriented MOF films were covalently modified with the fluorescent dye Rhodamine B inside the pore system, as demonstrated with size-selective fluorescence quenching studies. Our study suggests that mesoporous metal-organic frameworks are promising hosts for the covalent attachment of numerous functional moieties in a molecularly designed crystalline environment.

引用

页码：3899 / 3901

页数：3

共 19 条

[1] Luminescent metal-organic frameworks [J].

Allendorf, M. D. ;

Bauer, C. A. ;

Bhakta, R. K. ;

Houk, R. J. T. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1330-1352

[2] Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3•xH2O tunable with functionalized self-assembled monolayers [J].

Biemmi, Enrica ;

Scherb, Camilla ;

Bein, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8054-+

[3] Multiple Core-Shell Functionalized Colloidal Mesoporous Silica Nanoparticles [J].

Cauda, Valentina ;

Schlossbauer, Axel ;

Kecht, Johann ;

Zuerner, Andreas ;

Bein, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (32) :11361-11370

[4] Modifying MOFs: new chemistry, new materials [J].

Cohen, Seth M. .

CHEMICAL SCIENCE, 2010, 1 (01) :32-36

[5] GROWTH OF ORIENTED MOLECULAR-SIEVE CRYSTALS ON ORGANOPHOSPHONATE FILMS [J].

FENG, S ;

BEIN, T .

NATURE, 1994, 368 (6474) :834-836

[6] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[7] PHOTOINDUCED ELECTRON-TRANSFER QUENCHING OF RHODAMINE-B IN POLYMER-FILMS [J].

FISCHER, AB ;

BRONSTEINBONTE, I .

JOURNAL OF PHOTOCHEMISTRY, 1985, 30 (04) :475-485

[8] Metal-Organic Framework Materials as Chemical Sensors [J].

Kreno, Lauren E. ;

Leong, Kirsty ;

Farha, Omar K. ;

Allendorf, Mark ;

Van Duyne, Richard P. ;

Hupp, Joseph T. .

CHEMICAL REVIEWS, 2012, 112 (02) :1105-1125

[9] Chemistry of SURMOFs: Layer-Selective Installation of Functional Groups and Post-synthetic Covalent Modification Probed by Fluorescence Microscopy [J].

Liu, Bo ;

Ma, Mingyan ;

Zacher, Denise ;

Betard, Angelique ;

Yusenko, Kirill ;

Metzler-Nolte, Nils ;

Woell, Christof ;

Fischer, Roland A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (06) :1734-1737

[10] The pervasive chemistry of metal-organic frameworks [J].

Long, Jeffrey R. ;

Yaghi, Omar M. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1213-1214

← 1 2 →