Tris(1H-imidazole-κN3)(thiodiacetato-κ3O,S,O′)-nickel(II) monohydrate

被引：6

作者：

Pan, TT ^{[1
]}

Su, JR ^{[1
]}

Xu, DJ ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S160053680502194X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Ni(C4H4O4S)(C3H4N2)3](H2O)-H-., displays a distorted octahedral NiN3O2S coordination geometry, formed by three imidazole ( imid) ligands and one thiodiacetate dianion. The Ni-II atom is displaced from one of the imid planes, and the angle between the corresponding Ni-N bond and the imid plane is 21.94 (19)degrees. This spatial orientation is stabilized by an intermolecular C-H-...pi interaction between one imid ligand and the C-H bond of an adjacent imid ligand.

引用

页码：M1576 / M1578

页数：3

共 11 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].