Recent advances of polar transition-metal sulfides host materials for advanced lithium-sulfur batteries

被引：42
作者：
Chen, Liping [1 ,2 ]
Li, Xifei [1 ,2 ]
Xu, Yunhua [3 ,4 ]
机构：
[1] Xian Univ Technol, Inst Adv Electrochem Energy, Xian 710048, Shaanxi, Peoples R China
[2] Xian Univ Technol, Sch Mat Sci & Engn, Xian 710048, Shaanxi, Peoples R China
[3] Xian Univ Technol, Collaborat Innovat Ctr Modern Equipment & Green M, Xian 710048, Shaanxi, Peoples R China
[4] Yulin Univ, 4 Chongwen Rd, Yulin 719000, Shaanxi, Peoples R China
来源：
FUNCTIONAL MATERIALS LETTERS | 2018年 / 11卷 / 06期
关键词：
Lithium sulfur batteries; transition-metal sulfides; shuttle effect; redox kinetic; LI-S; CATHODE MATERIALS; PERFORMANCE; POLYSULFIDE; GRAPHENE; COMPOSITES; SURFACE; HYBRID; CONVERSION; CAPACITY;
D O I：
10.1142/S1793604718400106
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Lithium sulfur batteries (LSBs) have been one of the most promising second batteries for energy storage. However, the commercialization of LSBs is still hindered by low sulfur utilization and poor cycling stability, resulting from shuttle effect and low redox kinetics of lithium polysulfides (LiPSs). Significant progress has been made over the years in enhancing the batteries performances and tap density with the transition-metal sulfides as sulfur host or additive in LSBs. In this review, we present the recent advances in the use of various nanostructured transition-metal sulfides applied in LSBs, and also focus on the interaction mechanisms of polar transition-metal sulfides with LiPSs and its catalysis for the redox of LiPSs. It may provide avenues for the application of transition-metal sulfides in LSBs. The challenges and perspectives of transition-metal sulfides are also addressed.
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页数：7
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