Sustainable hydrogen production from steam reforming of bio-oil model compound based on carbon deposition/elimination

Steam reforming of crude bio-oil or some heavy component present in bio-oil is a great challenge for sustainable hydrogen production due to the extensive coke formation and catalyst deactivation. Catalyst regeneration will be an unavoidable operation in this process. In this paper, m-cresol (a model compound derived from bio-oil) was steam reformed on commercial Ni-based catalyst. Two conventional carbon elimination methods for coked catalyst were applied and the results showed that sustainable hydrogen production can be obtained based on carbon deposition/elimination. The carbon deposition can be gasified easily under certain temperature. The activity of regenerated catalyst samples can be nearly recovered as the fresh ones. Under the reaction conditions of 850 C and steam to carbon ratio 5:1, >66% hydrogen mole fraction, >81% hydrogen yield, and >97% carbon conversion can be achieved based on regenerated catalyst. Catalyst characterization indicated that the loss of active metal can be considered as the main reason for tiny activity drop. Ni redispersion and Fe contamination may be another two factors that influence catalyst activity. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.