Quaternary Fe-based bulk metallic glasses with a diameter of 5 mm

被引:32
作者
Han, Z. [1 ]
Zhang, J. [1 ]
Li, Y. [1 ]
机构
[1] Natl Univ Singapore, Fac Engn, Dept Mat Sci & Engn, Singapore 117576, Singapore
关键词
composites; glasses; metallic; microstructure;
D O I
10.1016/j.intermet.2007.05.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bulk metallic glasses with a diameter of 5 mm were obtained by drop casting in the quaternary Fe-B-Y-Nb and Fe-B-Y-Mo systems. Starting from the best glass former Fe71.2B24Y4.8 in the ternary Fe-B-Y system, the search quickly led to the discovery of the quaternary good glass formers (Fe71.2B24Y4.8)(96)Nb-4, (Fe73.2B22Y4.8)(95)Mo-5 and (Fe70.7B24Y5.3)(95)Mo-5 after trying only around a dozen of alloys. No obvious glass transition event was observed for these quaternary alloys. No Nb and Mo containing crystalline phases were detected in the alloys studied. The potential beneficial effects of Nb and Mo in enhancing the glass forming ability (GFA) of the Fe-B-Y alloy system are discussed. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1447 / 1452
页数:6
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