Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides

被引：357

作者：

Rossin, Andrea ^{[1
]}

Peruzzini, Maurizio ^{[1
]}

机构：

[1] ICCOM CNR, Inst Chem Organometall Cpds, Via Madonna Piano 10, I-50019 Florence, Italy

来源：

CHEMICAL REVIEWS | 2016年 / 116卷 / 15期

关键词：

DIHYDROGEN PINCER COMPLEX; HYDROGEN STORAGE TANK; H BOND ACTIVATION; CATALYTIC DEHYDROGENATION; DIMETHYLAMINE-BORANE; TRANSITION-METAL; DEHYDROCOUPLING REACTIONS; THERMAL-DECOMPOSITION; AMIDOBORANE COMPLEXES; AMINOBORANE COMPLEXES;

D O I：

10.1021/acs.chemrev.6b00043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review is a comprehensive survey of the last 10 years of research on ammonia borane and amine borane dehydrogenation mediated by complex metal hydrides (CMHs), within the broader context of chemical hydrogen storage. The review also collects those cases where CMHs are the catalyst spent form or its resting state. Highlights on the reaction mechanism (strictly dependent on the CMH of choice) and the catalysts efficiency (in terms of equivalents of H-2 produced and relative reaction rates) are provided throughout the discussion.

引用

页码：8848 / 8872

页数：25

共 138 条

[81] Synthesis of Group IV (Zr, Hf)-Group VIII (Fe, Ru) Heterobimetallic Complexes Bearing Metallocenyl Diphosphine Moieties and Their Application to Catalytic Dehydrogenation of Amine-Boranes [J].

Miyazaki, Takamasa ;

Tanabe, Yoshiaki ;

Yuki, Masahiro ;

Miyake, Yoshihiro ;

Nishibayashi, Yoshiaki .

ORGANOMETALLICS, 2011, 30 (08) :2394-2404

[82] Hydrazine Borane and Hydrazinidoboranes as Chemical Hydrogen Storage Materials [J].

Moury, Romain ;

Demirci, Umit B. .

ENERGIES, 2015, 8 (04) :3118-3141

[83] Dehydrogenation of a tertiary amine-borane by a rhenium complex [J].

Muhammad, Sohail ;

Moncho, Salvador ;

Brothers, Edward N. ;

Bengali, Ashfaq A. .

CHEMICAL COMMUNICATIONS, 2014, 50 (44) :5874-5877

[84] Exploring the Limits of Catalytic Ammonia-Borane Dehydrogenation Using a Bis(N-heterocyclic carbene) Iridium(III) Complex [J].

Nelson, David J. ;

Truscott, Byron J. ;

Egbert, Jonathan D. ;

Nolan, Steven P. .

ORGANOMETALLICS, 2013, 32 (13) :3769-3772

[85] Origin of Binding of Ammonia-Borane to Transition-Metal-Based Catalysts: An Insight from the Charge and Energy Decomposition Method ETS-NOCV [J].

Parafiniuk, Monika ;

Mitoraj, Mariusz Pawel .

ORGANOMETALLICS, 2013, 32 (15) :4103-4113

[86] Catalyzed dehydrogenation of ammonia-borane by iridium dihydrogen pincer complex differs from ethane dehydrogenation [J].

Paul, Ankan ;

Musgrave, Charles B. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (43) :8153-8156

[87] Ammonia borane as an efficient and lightweight hydrogen storage medium [J].

Peng, Bo ;

Chen, Jun .

ENERGY & ENVIRONMENTAL SCIENCE, 2008, 1 (04) :479-483

[88] Turning Perspective in Photoelectrocatalytic Cells for Solar Fuels [J].

Perathoner, Siglinda ;

Centi, Gabriele ;

Su, Dangsheng .

CHEMSUSCHEM, 2016, 9 (04) :345-357

[89]

Peruzzini M., 2001, RECENT ADV HYDRIDE C

[90] Soluble Boron-Nitrogen High Polymers from Metal-Complex-Catalyzed Amine Borane Dehydrogenation [J].

Pons, Vincent ;

Baker, R. Tom .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (50) :9600-9602

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