Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides

被引：357

作者：

Rossin, Andrea ^{[1
]}

Peruzzini, Maurizio ^{[1
]}

机构：

[1] ICCOM CNR, Inst Chem Organometall Cpds, Via Madonna Piano 10, I-50019 Florence, Italy

来源：

CHEMICAL REVIEWS | 2016年 / 116卷 / 15期

关键词：

DIHYDROGEN PINCER COMPLEX; HYDROGEN STORAGE TANK; H BOND ACTIVATION; CATALYTIC DEHYDROGENATION; DIMETHYLAMINE-BORANE; TRANSITION-METAL; DEHYDROCOUPLING REACTIONS; THERMAL-DECOMPOSITION; AMIDOBORANE COMPLEXES; AMINOBORANE COMPLEXES;

D O I：

10.1021/acs.chemrev.6b00043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review is a comprehensive survey of the last 10 years of research on ammonia borane and amine borane dehydrogenation mediated by complex metal hydrides (CMHs), within the broader context of chemical hydrogen storage. The review also collects those cases where CMHs are the catalyst spent form or its resting state. Highlights on the reaction mechanism (strictly dependent on the CMH of choice) and the catalysts efficiency (in terms of equivalents of H-2 produced and relative reaction rates) are provided throughout the discussion.

引用

页码：8848 / 8872

页数：25

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