CMC as a stabiliser of metal oxide suspensions

被引:29
作者
Grzadka, E. [1 ]
Matusiak, J. [1 ]
Bastrzyk, A. [2 ]
Polowczyk, I. [2 ]
机构
[1] Marie Curie Sklodowska Univ, Fac Radiochem & Chem Colloids, Dept Chem, M Sklodowskiej Curie 3 Sq, PL-20031 Lublin, Poland
[2] Wroclaw Univ Sci & Technol, Dept Chem, Dept Chem Engn, Wybrzeze Wyspianskiego 27, PL-50370 Wroclaw, Poland
关键词
Carboxymethyl cellulose; Zirconia; Alumina; Stabilization; Flocculation; CARBOXYMETHYL CELLULOSE ADSORPTION; NANOCOMPOSITE MEMBRANES; ALUMINA PARTICLES; GUAR GUM; TALC; DISPERSIONS; MECHANISM; AFM;
D O I
10.1007/s10570-019-02930-y
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Stabilizating properties of carboxymethyl cellulose (CMC) towards nano-zirconia (n-ZrO2) and alumina (Al2O3) were studied using spectrophotometric, turbidimetric and zeta potential measurements. The obtained results prove that CMC might be successfully used as a stabilizer of nano-zirconia, however, its stabilizing properties are much lower in the case of the alumina + containing systems. Due to the fact that CMC is an anionic polymer the influence of not only the polymer concentration but also of pH on stability of the metal oxide suspensions was studied. It turned out that the CMC concentration has larger influence on stability of the metal oxide suspensions than pH. In order to estimate the stabilization mechanism in the studied systems the adsorption of CMC on both oxides was conducted using the spectrophotometric method confirmed by FTIR. The obtained results could find practical applications particularly in the fields of ceramics and catalysis.
引用
收藏
页码:2225 / 2236
页数:12
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