Copper-mediated ortho C-H sulfonylation of benzoic acid derivatives with sodium sulfinates

被引：104

作者：

Liu, Jidan ^{[1
]}

Yu, Lin ^{[1
]}

Zhuang, Shaobo ^{[1
]}

Gui, Qingwen ^{[1
]}

Chen, Xiang ^{[1
]}

Wang, Wenduo ^{[1
]}

Tan, Ze ^{[1
]}

机构：

[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 29期

基金：

中国国家自然科学基金;

关键词：

UNSYMMETRICAL DIARYL SULFONES; EFFICIENT METHOD; BOND FORMATION; ARYL; ARENES; AMIDATION; SALTS; ALKYNYLATION; INHIBITORS; C(SP(3))-H;

D O I：

10.1039/c5cc00202h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper-mediated direct ortho C-H bond sulfonylation of benzoic acid derivatives with sodium sulfinates was achieved by employing an 8-aminoquinoline moiety as the bidentate directing group. Various aryl sulfones were synthesized in good yields with excellent regioselectivity.

引用

页码：6418 / 6421

页数：4

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