Highly regioselective synthesis of aryl chalcogenides through C-H functionalization of arenes

被引：82

作者：

Cheng, Jun-Hao ^{[1
]}

Yi, Chih-Lun ^{[1
]}

Liu, Tsung-Jui ^{[1
]}

Lee, Chin-Fa ^{[1
]}

机构：

[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 67期

关键词：

SULFUR BOND FORMATION; IRIDIUM-CATALYZED BORYLATION; 1,3-DISUBSTITUTED ARENES; DIARYL DISELENIDES; COUPLING REACTION; DIRECT ARYLATION; BORONIC ACIDS; TE BOND; THIOLS; HALIDES;

D O I：

10.1039/c2cc33950a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report here the regioselective synthesis of aryl chalcogenides through the iridium-catalyzed meta C-H borylation followed by copper-catalyzed C-S coupling reaction with chalcogenide sources in one pot, giving the 3,5-disubstituted aryl chalcogenides with high regioselectivity and good yields.

引用

页码：8440 / 8442

页数：3

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