Macrocyclic polyethers as probes to assess and understand alkali metal cation-π interactions

被引：152
|
作者：
Gokel, GW
Barbour, LJ
De Wall, SL
Meadows, ES
机构：
[1] Washington Univ, Sch Med, Dept Mol Biol & Pharmacol, Bioorgan Chem Program, St Louis, MO 63110 USA
[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
来源：
COORDINATION CHEMISTRY REVIEWS | 2001年 / 222卷
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
alkali metal; arene; cation-pi interaction; host-guest; crown ether; lariat ether;
D O I：
10.1016/S0010-8545(01)00380-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cation-pi interactions of alkali metals with arenes have been known in the gas phase for two decades but solid-state structural data have become available only recently. The quest for solid-state evidence is described here. Complexation of Na+ and K+ by arene-terminated lariat ethers has provided important insights into the cation-pi interaction. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：127 / 154
页数：28
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