Synthesis of oligomeric axially bridged ruthenium phthalocyanines and 2,3-naphthalocyanines

被引：0

作者：

Knecht, S ^{[1
]}

Polley, R ^{[1
]}

Hanack, M ^{[1
]}

机构：

[1] UNIV TUBINGEN, INST ORGAN CHEM, LEHRSTUHL ORGAN CHEM 2, D-72076 TUBINGEN, GERMANY

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1996年 / 10卷 / 08期

关键词：

naphthalocyanine; ruthenium; bridged; oligomers; solid state; NMR; conductivity;

D O I：

10.1002/(SICI)1099-0739(199610)10:8<649::AID-AOC525>3.0.CO;2-K

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Bridged 2,3-naphthalocyaninatoruthenium oligomers {[MacRu(L)](n)} were synthesized and characterized using solid-state methods. For comparison, soluble t-butyl substituted phthalocyaninatoruthenium oligomers were prepared and their chain length examined by H-1 NMR spectroscopy. The powder conductivities of ail bridged compounds ([MacRu(L)](n)) were measured and the dependence of the conductivities on the bridging ligands is discussed.

引用

页码：649 / 660

页数：12