Synthesis of oligomeric axially bridged ruthenium phthalocyanines and 2,3-naphthalocyanines

被引：0
作者：
Knecht, S [1 ]
Polley, R [1 ]
Hanack, M [1 ]
机构：
[1] UNIV TUBINGEN, INST ORGAN CHEM, LEHRSTUHL ORGAN CHEM 2, D-72076 TUBINGEN, GERMANY
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 1996年 / 10卷 / 08期
关键词：
naphthalocyanine; ruthenium; bridged; oligomers; solid state; NMR; conductivity;
D O I：
10.1002/(SICI)1099-0739(199610)10:8<649::AID-AOC525>3.0.CO;2-K
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Bridged 2,3-naphthalocyaninatoruthenium oligomers {[MacRu(L)](n)} were synthesized and characterized using solid-state methods. For comparison, soluble t-butyl substituted phthalocyaninatoruthenium oligomers were prepared and their chain length examined by H-1 NMR spectroscopy. The powder conductivities of ail bridged compounds ([MacRu(L)](n)) were measured and the dependence of the conductivities on the bridging ligands is discussed.
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页码：649 / 660
页数：12
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