Highly reinforced, low magnetic and biaxially textured Ni-7 at.%W/Ni-12 at.%W multi-layer substrates developed for coated conductors

Mechanically strengthened, highly cube textured Ni-7 at.%W/Ni-12at.%W multi-layer substrates developed for coated conductors have been prepared by the advanced spark plasma sintering technique. The key innovation for developing this weakly magnetic and reinforced substrate was to use a new powder metallurgy and sintering route to bond multi-layers of Ni7W/Ni12W/Ni7W together in order to get an initial ingot, followed by the optimized cold working and annealing. Particular efforts were made in view of the optimization of the design, pressing as well as the heat treatment processes of the starting ingots to obtain a chemically gradient composite bulk, thus ensuring the subsequent cold deformation. The produced composite substrates have a strong < 001 > {100} texture on Ni7W outer layers. The percentage of the biaxially orientated grains within a misorientation angle of 10 degrees is as high as 97.5%, while the length percentage of low-angle grain boundaries ranging from 2 degrees to 10 degrees in the composite substrate reaches 87.2%. Moreover, the yield strength sigma(0.2) of the tape approaches 333 MPa, and the saturation magnetization is substantially reduced by 81.6% at 77 K when compared to that of a commercial used Ni5W substrate.