3,6-Bis(4-nitro-1,2,5-oxadiazol-3-yl)-1,4,2,5-dioxadiazene (BNDD): A Powerful Sensitive Explosive

被引：32

作者：

Leonard, Philip W. ^{[1
]}

Pollard, Colin J. ^{[1
]}

Chavez, David E. ^{[1
]}

Rice, Betsy M. ^{[2
]}

Parrish, Damon A. ^{[3
]}

机构：

[1] Los Alamos Natl Lab, Weap Expt Div, Los Alamos, NM 87545 USA

[2] USA, Res Lab, Aberdeen, MD 20783 USA

[3] USN, Res Lab, Struct Matter Lab, Washington, DC 20375 USA

来源：

SYNLETT | 2011年 / 14期

关键词：

explosives; furazan; heterocycles; nitrogen; oxidation;

D O I：

10.1055/s-0030-1261169

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The explosive 3,6-bis(4-nitro-1,2,5-oxadiazol-3-yl)1,4,2,5- dioxadiazene (BNDD) was synthesized by oxidation of the corresponding diamine using hydrogen peroxide in sulfuric acid with sodium tungstate. The product exhibited detonations during sensitivity testing at low insult; the material is shock and friction sensitive. The synthesis of BNDD should only be pursued by knowledgeable researchers exercising extreme caution.

引用

页码：2097 / 2099

页数：3

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