High-specific-capacity molybdate anode materials for lithium-ion batteries with good low-temperature performance

Molybdate materials have proved to be potential anode because of their superior specific capacity, stable three-dimensional framework structure and fast lithium-ion transport ability. However, the low-temperature properties and electrochemical reaction mechanism still lack in-depth research. Here, two molybdate materials, LiCr(MoO4)(2)/C and Li3Cr(MoO4)(3)/C, are synthesized by a sample ball-milling assisted high-temperature solid state method and studied as anode materials for lithium-ion batteries (LIBs) at room temperature and low temperature. Between 0.01 V and 3.00 V, LiCr(MoO4)(2)/C and Li3Cr(MoO4)(3)/C exhibit high specific capacities of 1158 and 1077 mA h.g(-1) at 50 mA.g(-1) at 25 degrees C, respectively. LiCr(MoO4)(2)/C delivers a high specific capacity of 352 mA h.g(-1) at a high current density of 5000 mA.g(-1). After 500 cycles, LiCr (MoO4)(2)/C and Li3Cr(MoO4)(3)/C both retain reversible capacities over 600 mA h.g(-1) at 250 mA.g(-1). Even at low temperature of 0 degrees C, - 10 degrees C, - 20 degrees C, Li3Cr(MoO4)(3)/C still delivers high capacities of 1061, 891 and 742 mA h.g(-1), respectively. Ex-situ X-ray diffraction (XRD) is conducted to study the electrochemical reaction mechanism. Moreover, low-temperature cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) tests are used to explore the limitations of low-temperature performance. This work provides low-temperature anode material for LIBs and deepens the understanding of low-temperature performance. (C) 2022 Elsevier B.V. All rights reserved.