Synthesis and comparison of extraction properties of p-tert-butylcalix[n]arene nitrile derivatives for selected metals and dichromate anions

被引：3
|
作者：
Kocak, Ahmet [1 ]
Ceran, Saadet [1 ]
Memon, Shahabuddin [2 ]
Yilmaz, Mustafa [1 ]
机构：
[1] Selcuk Univ, Dept Chem, Fac Arts & Sci, TR-42075 Konya, Turkey
[2] Univ Sindh, Natl Ctr Excellence Anal Chem, Jamshoro, Pakistan
来源：
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY | 2008年 / 45卷 / 06期
关键词：
calixarenes; toxicity; transition metal ions; dichromate anion; selectivity; liquid-liquid extraction;
D O I：
10.1080/10601320801977657
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The article describes the syntheses and extraction properties of two p-tert-butylcalix[6]arene nitrile derivatives (3 and 4). The trinitrile derivative 3 has been synthesized from 5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41,42-hexahydroxy-calix[6]arene 1. The compound 1 was directly converted to its hexanitrile derivative (4). In these syntheses, it was considered to explore the role of nitrile sites in the extraction of various metal cations and HCr2O7-/Cr2O72- anions. The liquid-liquid extraction properties of 3 and 4 towards selected alkali/transition metal cations and HCr2O7-/Cr2O72- anions are reported. It has been observed that receptor 3 does not extract alkali/transition metal cations effectively, but shows affinity towards HCr2O7-/Cr2O72- anions at low pH. The compound 4 is an effective form for transferring Ni2+ selectively, while it shows poor transferring ability for HCr2O7-/Cr2O72- anions from an aqueous into a dichloromethane layer. It was observed that the cavity size of the calix[n]arenes and the cooperativity of the functionalities play important roles in two phase extraction systems.
引用
收藏
页码：440 / 444
页数：5
相关论文
共 50 条
  • [41] Contribution to the Complexation of Some Univalent Metal Cations with p-Tert-Butylcalix[4]arene-Tetrakis(N,N-Diethylacetamide) in Nitrobenzene Saturated with Water
    Makrlik, E.
    Budka, J.
    Vanura, P.
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2011, 225 (02): : 271 - 276
  • [42] Solution and solid-state conformations of 1,5-pyridine and 1,5-phenanthroline-bridged p-tert-butylcalix[8]arene derivatives
    Hernandez, David J.
    Vazquez-Lima, Hugo
    Guadarrama, Patricia
    Martinez-Otero, Diego
    Castillo, Ivan
    TETRAHEDRON LETTERS, 2013, 54 (36) : 4930 - 4933
  • [43] p-tert-Butylcalix[4]arene tetrakis(N,N-dimethylacetamide) as a second ligand in the complexation of trivalent lanthanoids with thenoyltrifluoroacetone in solution and investigation of a solid Eu(III) complex
    Atanassova, Maria
    Vassilev, Nikolay
    Dukov, Ivan
    SEPARATION AND PURIFICATION TECHNOLOGY, 2011, 78 (02) : 214 - 219
  • [44] Synthesis of Amino-Substituted p-tert-Butylcalix[4]arene for the Removal of Chicago Sky Blue and Tropaeolin 000 Azo Dyes from Aqueous Environment
    Kamboh, Muhammad Afzal
    Akoz, Enise
    Memon, Shahabuddin
    Yilmaz, Mustafa
    WATER AIR AND SOIL POLLUTION, 2013, 224 (02):
  • [45] Synthesis, crystal structures, cation-binding properties and the influence of intramolecular C-H•••O interactions on the complexation behaviour of a family of cone p-tert-butylcalix[4]arene-crown-5 compounds
    Agnihotri, Pragati
    Suresh, Eringathodi
    Paul, Parimal
    Ghosh, Pushpito K.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 17 (17) : 3369 - 3381
  • [46] p-tert-Butylcalix[8]arene catalysed synthesis of 3,5-dinitrothiophene scaffolds: antiproliferative effect of some representative compounds on selective anticancer cell lines
    Sarkar, Piyali
    Maiti, Samares
    Ghosh, Krishnendu
    Sengupta , Sumita
    Butcher, Ray J.
    Mukhopadhyay, Chhanda
    TETRAHEDRON LETTERS, 2014, 55 (05) : 996 - 1001
  • [47] Lower rim substituted p-tert-butyl-calix[4]arene. Part 16. Synthesis of 25,26,27,28-tetrakis( piperidinylthiocarbonylmethylene)-p-tert-butylcalix[4]arene and its interaction with metal ions
    Kulesza, Joanna
    Guzinski, Marcin
    Hubscher-Bruder, Veronique
    Arnaud-Neu, Francoise
    Bochenska, Maria
    POLYHEDRON, 2011, 30 (01) : 98 - 105
  • [48] Synthesis and extraction properties of 1,3,5-O-trimethyl-2,4,6-tri-O-hydroxamic acid p-tert-butyl calix[6]arene
    Bennouna, L
    Vicens, J
    Asfari, Z
    Yahyaoui, A
    Burgard, M
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2001, 40 (1-2) : 95 - 98
  • [49] Synthesis and Extraction Properties of 1,3,5-O-trimethyl-2,4,6-tri-O-hydroxamic Acid p-tert-butyl Calix[6]arene
    L. Bennouna
    J. Vicens
    Z. Asfari
    A. Yahyaoui
    M. Burgard
    Journal of inclusion phenomena and macrocyclic chemistry, 2001, 40 : 95 - 98
  • [50] Metal ion extraction by cone p-tert-butylcalix[4]arene-1,3-crown-5 with two N-(X)sulfonyl carbamoylmethoxy side arms and-1,3-monothiacrown-5 analogues
    Yang, Yanfei
    Cao, Xiaodan
    Surowiec, Kazimierz
    Bartsch, Richard A.
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2014, 78 (1-4) : 387 - 395
12345