Alum catalyzed simple and efficient synthesis of 5-arylidene-2,4-thiazolidinedione in aqueous media

被引：34

作者：

Shelke, Kiran F. ^{[1
]}

Sapkal, Suryakant B. ^{[1
]}

Kakade, Gopal K. ^{[1
]}

Sadaphal, Sandip A. ^{[1
]}

Shingate, Bapurao B. ^{[1
]}

Shingare, Murlidhar S. ^{[1
]}

机构：

[1] Dr Babasaheb Ambedkar Marathwada Univ, Dept Chem, Aurangabad 431004, Maharashtra, India

来源：

GREEN CHEMISTRY LETTERS AND REVIEWS | 2010年 / 3卷 / 01期

关键词：

Knoevenagel condensation; alum; 2,4-thiazolidinedione; aromatic aldehyde; aqueous media; ONE-POT SYNTHESIS; CENTER-DOT 12H(2)O; KNOEVENAGEL CONDENSATION; REUSABLE CATALYST; ACID; KAL(SO4)(2)CENTER-DOT-12H(2)O; SYSTEM; WATER;

D O I：

10.1080/17518250903478345

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alum (KAl(SO4)(2)center dot 12H(2)O) is an inexpensive, efficient, and non-toxic catalyst used for the synthesis of 5-arylidine-2,4-thiazolidinediones by the Knoevenagel condensation of aromatic aldehydes with 2,4-thiazolidinedione in aqueous media at 90 degrees C. This method affords the 5-arylidine-2,4-thiazolidinediones in short reaction times, high yields, and green aspects by avoiding toxic catalysts and hazardous solvents.

引用

页码：17 / 21

页数：5

共 30 条

[11] Green synthesis of 5-benzylidene rhodanine derivatives catalyzed by 1-butyl-3-methyl imidazolium hydroxide in water [J].

Gong, Kai ;

He, Zhi-Wei ;

Xu, Ying ;

Fang, Dong ;

Liu, Zu-liang .

MONATSHEFTE FUR CHEMIE, 2008, 139 (08) :913-915

[12] Knoevenagel condensation reactions in an ionic liquid [J].

Hangarge, RV ;

Jarikote, DV ;

Shingare, MS .

GREEN CHEMISTRY, 2002, 4 (03) :266-268

[13] Water mediated uncatalyzed facile synthesis of ylidenenitriles of 4-oxo-(4H)-1-benzopyran-3-carbaldehyde [J].

Hangarge, RV ;

Sonwane, SA ;

Jarikote, DV ;

Shingare, MS .

GREEN CHEMISTRY, 2001, 3 (06) :310-312

[14]

Jones G., 1967, ORGANICREACTIONS, V15, P204, DOI 10.1002/0471264180.or015.02

[15]

LIMA MCA, 1992, PHARMAZIE, V47, P182

[16] An efficient condensation of 4-oxo-4H-benzopyran-3-carbaldehydes with 3-methyl-1-phenyl-1H-pyrazol-5 (4H)-one [J].

Madje, BR ;

Shindalkar, SS ;

Ware, MN ;

Shingare, MS .

ARKIVOC, 2005, :82-86

[17] Alum-catalyzed one-pot solventless synthesis of 1,5-benzodiazepines [J].

Mahajan, Deepali ;

Naqvi, Tahira ;

Sharma, Rattan Lal ;

Kapoor, Kamal K. .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2008, 61 (02) :159-162

[18] An efficient method for Knoevenagel condensation: a facile synthesis of 5-arylidenyl 2,4-thiazolidinedione [J].

Mahalle, Shital R. ;

Netankar, Prashant D. ;

Bondge, Sandipan P. ;

Mane, Ramrao A. .

GREEN CHEMISTRY LETTERS AND REVIEWS, 2008, 1 (02) :103-106

[19] Potassium aluminum sulfate (alum): an efficient catalyst for the one-pot synthesis of trisubstituted imidazoles [J].

Mohammadi, Ali A. ;

Mivechi, Mersede ;

Kefayati, Hassan .

MONATSHEFTE FUR CHEMIE, 2008, 139 (08) :935-937

[20] Glyoxylic acid as catalyst: A simple selective synthesis of 1,2-disubstituted benzimidazoles in aqueous media [J].

Pawar, Shivaji S. ;

Dekhane, Deepak V. ;

Shingare, Murlidhar S. ;

Thore, Shivaji N. .

CHINESE CHEMICAL LETTERS, 2008, 19 (09) :1055-1058

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